Boiling is the process by which a liquid turns into a vapor when it is heated to it’s boiling point. The change from a liquid phase to a gaseous phase occurs when the vapor pressure of the liquid is equal to the atmospheric pressure exerted on the liquid. Boiling is a physical change and molecules are not chemically altered during the process.
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Answer : The rate constant at 785.0 K is, 
Explanation :
According to the Arrhenius equation,

or,
![\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7BK_1%7D%29%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= rate constant at
= 
= rate constant at
= ?
= activation energy for the reaction = 262 kJ/mole = 262000 J/mole
R = gas constant = 8.314 J/mole.K
= initial temperature = 
= final temperature = 
Now put all the given values in this formula, we get:
![\log (\frac{K_2}{6.1\times 10^{-8}s^{-1}})=\frac{262000J/mole}{2.303\times 8.314J/mole.K}[\frac{1}{600.0K}-\frac{1}{785.0K}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7B6.1%5Ctimes%2010%5E%7B-8%7Ds%5E%7B-1%7D%7D%29%3D%5Cfrac%7B262000J%2Fmole%7D%7B2.303%5Ctimes%208.314J%2Fmole.K%7D%5B%5Cfrac%7B1%7D%7B600.0K%7D-%5Cfrac%7B1%7D%7B785.0K%7D%5D)

Therefore, the rate constant at 785.0 K is, 
Liquids have free and fast moving particles. Liquids do not take a specific shape unless they are enclosed such as in a bottle. Anyway, since they are free flowing when they freeze, their movement becomes very slow. Eventually the particles will not have room to move as they used to and will be held in one place. The particles are still moving but they are only shaking or vibrating in the same place. You can't even tell this movement is happening, and that is what happens when liquid freezes.
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