Answer:
The correct answer is B.
Explanation:
Heterogeneous equilibrium is that in which reagents and products are present in more than one phase.
When the reaction is carried out in a closed container, three equilibrium phases are present: solid magnesium oxide, solid magnesium sulfate and gaseous sulfur trioxide.
Hence, the equilibrium contant is given by:
![K=\frac{[MgSO_4]}{[MgO][SO_3]} =\frac{1}{[SO_3]}](https://tex.z-dn.net/?f=K%3D%5Cfrac%7B%5BMgSO_4%5D%7D%7B%5BMgO%5D%5BSO_3%5D%7D%20%3D%5Cfrac%7B1%7D%7B%5BSO_3%5D%7D)
The concentrations in the equilibrium equation are the relationships of the real concentrations between the concentrations in the standard state. Since the standard state of a pure solid is the pure solid itself, the ratio of concentrations for a pure solid is equal to one.
Now, we analyse each statement:
I) As the reaction is endothermic (ΔH>0), increasing the temperature shifts the balance to the right because excess heat will be used to form more products.
II) Increasing the volume will decrease the concentration of SO₃, so Q>K and then this shifts the balance to the left.
III) As it is a heterogeneous balance, adding MgO will not affect the balance.
IV) Removing SO3 will decrease its concentration and therefore the reaction equilibrium will shift to the left.
Answer:
2.5 L will be the volume of HNO₃
Explanation:
To find out the total volume of nitric acid in liters we begin from molarity.
HNO₃ solution is 0.10 M
This means that 0.10 moles are contained in 1L of solution.
As we used 0.25 moles of nitric, let's determine the volume by a rule of three:
0.10 moles of nitric acid are contained in 1L of solution
0.25 moles of nitric acid will be contained in (0.25 . 1) / 0.1 = 2.5 L
Answer:
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In accordance with the Le Chatelier's Principle, when the concentration of the aluminum increases then the equilibrium would shift to the right. It will produce more products since there are more reactants available and also collision is more frequent.