The chemists is another name for the periodic table
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Answer:
Phenols do not exhibit the same pka values as other alcohols;
They are generally more acidic.
Using the knowledge that hydrogen acidity is directly related to the stability of the anion formed, explain why phenol is more acidic than cyclohexane.
Explanation:
According to Bromsted=Lowry acid-base theory,
an acid is a substance that can release ions when dissolved in water.
So, acid is a proton donor.
If the conjugate base of an acid is more stable then, that acid is a strong acid.
In the case of phenol,
the phenoxide ion formed is stabilized by resonance.
The resonance in phenoxide ion is shown below:
Whereas in the case of cyclohexanol resonance is not possible.
So, cyclohexanol is a weak acid compared to phenol.
Answer:
Composition of the mixture:
%
%
Composition of the vapor mixture:
%
%
Explanation:
If the ideal solution model is assumed, and the vapor phase is modeled as an ideal gas, the vapor pressure of a binary mixture with and
molar fractions can be calculated as:
Where and
are the vapor pressures of the pure compounds. A substance boils when its vapor pressure is equal to the pressure under it is; so it boils when
. When the pressure is 0.60 atm, the vapor pressure has to be the same if the mixture is boiling, so:
With the same assumptions, the vapor mixture may obey to the equation:
, where P is the total pressure and y is the fraction in the vapor phase, so:
%
The fractions of B can be calculated according to the fact that the sum of the molar fractions is equal to 1.