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jenyasd209 [6]
3 years ago
13

When adjusted for any changes in ΔHΔH and ΔSΔS with temperature, the standard free energy change ΔG∘TΔGT∘Delta G_{T}^{\circ} at

2400 KK is equal to 1.22×105J/mol1.22×105J/mol . Calculate the equilibrium constant at 2400 KK .
Chemistry
1 answer:
STALIN [3.7K]3 years ago
4 0

The equilibrium constant is 0.0022.

Explanation:

The values given in the problem is

ΔG° = 1.22 ×10⁵ J/mol

T = 2400 K.

R = 8.314 J mol⁻¹ K⁻¹

The Gibbs free energy should be minimum for a spontaneous reaction and equilibrium state of any reaction is spontaneous reaction. So on simplification, the thermodynamic properties of the equilibrium constant can be obtained as related to Gibbs free energy change at constant temperature.

The relation between Gibbs free energy change with equilibrium constant is ΔG° = -RT ln K

So, here K is the equilibrium constant. Now, substitute all the given values in the corresponding parameters of the above equation.

We get,

1.22 * 10^{5} = - 8.314* 2400 * ln K

\\ 1.22 * 10^{5} = -19953.6 * ln K

ln K = \frac{-1.22*10^{5} }{19953.6} =-6.114\\\\k =e^{-6.114}=0.0022

So, the equilibrium constant is 0.0022.

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The heat of vaporization for benzaldehyde is 48.8 kj/mol, and its normal boiling point is 451.0 k. use this information to deter
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The vapor pressure of benzaldehyde at 61.5 °C is 70691.73 torr.

Explanation:

  • To solve this problem, we use Clausius Clapeyron equation: ln(P₁/P₂) = (ΔHvap / R) (1/T₁ - 1/T₂).
  • The first case: P₁ = 1 atm = 760 torr and T₁ = 451.0 K.
  • The second case: P₂ = <em>??? needed to be calculated</em> and T₂ = 61.5 °C = 334.5 K.
  • ΔHvap = 48.8 KJ/mole = 48.8 x 10³ J/mole and R = 8.314 J/mole.K.
  • Now, ln(P₁/P₂) = (ΔHvap / R) (1/T₁ - 1/T₂)
  • ln(760 torr /P₂) = (48.8 x 10³ J/mole / 8.314 J/mole.K) (1/451 K - 1/334.5 K)
  • ln(760 torr /P₂) = (5869.62) (-7.722 x 10⁻⁴) = -4.53.
  • (760 torr /P₂) = 0.01075
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So, The vapor pressure of benzaldehyde at 61.5 °C is 70691.73 torr.

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2 years ago
Silver chloride was reacted with magnesium hydroxide, in which magnesium displaced silver
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