Explanation:
The given data is as follows.
Current (I) = 3.50 amp, Mass deposited = 100.0 g
Molar mass of Cr = 52 g
It is known that 1 faraday of electricity will deposit 1 mole of chromium. As 1 faraday means 96500 C and 1 mole of Cr means 52 g.
Therefore, 100 g of Cr will be deposited by "z" grams of electricity.
![z \times 52 g = 96500 \times 100 g](https://tex.z-dn.net/?f=z%20%5Ctimes%2052%20g%20%3D%2096500%20%5Ctimes%20100%20g)
z = ![\frac{96500 \times 100 g}{52 g}](https://tex.z-dn.net/?f=%5Cfrac%7B96500%20%5Ctimes%20100%20g%7D%7B52%20g%7D)
= 185576.9 C
As we know that, Q = I × t
Hence, putting the given values into the above equation as follows.
Q = I × t
185576.9 C =
t = 53021.9 sec
Thus, we can conclude that 100 g of Cr will be deposited in 53021.9 sec.
The bond dissociation energy of the Cl - Cl bond is -958 kJ mol^-1.
<h3>What is the dissociation enthalpy?</h3>
Given that;
H-H bond energy = 435 kJ mol^-1
H-Cl bond energy = 431 kJ mol^-1
ΔHfO of HCL(g) = -92kJ mol^-1
Bond dissociation enthalpy of the Cl-Cl bond = x
-92 = 435 + 431 + x
x = -92 - (435 + 431)
x = -958 kJ mol^-1
Learn More about dissociation enthalpy:brainly.com/question/9998007?
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Answer:
A) 54.04%
B) 13-karat
Explanation:
A) From the problem we have
<em>1)</em> Mg + Ms = 9.40 g
<em>2)</em> Vg + Vs = 0.675 cm³
Where M stands for mass, V stands for volume, and g and s stand for gold and silver respectively.
We can rewrite the first equation using the density values:
<em>3)</em> Vg * 19.3 g/cm³ + Vs * 10.5 g/cm³ = 9.40
So now we have<em> a system of two equations</em> (2 and 3) <em>with two unknowns</em>:
We <u>express Vg in terms of Vs</u>:
We <u>replace the value of Vg in equation 3</u>:
- Vg * 19.3 + Vs * 10.5 = 9.40
- (0.675-Vs) * 19.3 + Vs * 10.5 = 9.40
- 13.0275 - 19.3Vs + 10.5Vs = 9.40
Now we <u>calculate Vg</u>:
- Vg + 0.412 cm³ = 0.675 cm³
We <u>calculate Mg from Vg</u>:
- 0.263 cm³ * 19.3 g/cm³ = 5.08 g
We calculate the mass percentage of gold:
- 5.08 / 9.40 * 100% = 54.04%
B)
We multiply 24 by the percentage fraction:
- 24 * 54.04/100 = 12.97-karat ≅ 13-karat
Answer:
According to Le-chatelier principle, equilibrium will shift towards left to minimize concentration of
and keep same equilibrium constant
Explanation:
In this buffer following equilibrium exists -
![NH_{3}(aq.)+H_{2}O(l)\rightleftharpoons NH_{4}^{+}(aq.)+OH^{-}(aq.)](https://tex.z-dn.net/?f=NH_%7B3%7D%28aq.%29%2BH_%7B2%7DO%28l%29%5Crightleftharpoons%20NH_%7B4%7D%5E%7B%2B%7D%28aq.%29%2BOH%5E%7B-%7D%28aq.%29)
So,
is involved in the above equilibrium.
When a strong base is added to this buffer, then concentration of
increases. Hence, according to Le-chatelier principle, above equilibrium will shift towards left to minimize concentration of
and keep same equilibrium constant.
Therefore excess amount of
combines with
to produce ammonia and water. So, effect of addition of strong base on pH of buffer gets minimized.