Second one i think.......
<span>Molality(m) or molal concentration is a measure
of concentration and it refers to amount of substance in a specified amount of
mass of the solvent. Used unit for molality is mol/kg which is also
sometimes denoted as 1 molal. It is equal to the moles of solute (the substance
being dissolved) divided by the kilograms of solvent (the substance used to
dissolve).</span>
Molarity(M) or molar concentration is also a
measure of concentration and represents the amount of substance per unit volume
of solution(number of moles per litre of solution. Used unit for molarity is
mol/L or M. A solution with a concentration of 1 mol/L is equivalent to 1 molar
(1 M).
Molality is preferred when
the temperature of the solution varies, because it does not depend on
temperature, (neither number of moles of solute nor mass of solvent will be affected
by changes of temperature), while molarity changes as temperature changes(volume
of solution changes as temperature changes).
The reaction between ammonium sulfate and calcium hydroxide is given below.
(NH₄)₂SO₄ + Ca(OH)₂ --> 2NH₃ + CaSO₄ + 2H₂O
From the balance equation, we can conclude that every 74 g of calcium sulfate reacted with enough amount of ammonium sulfate will yield 34 grams of ammonia. From the given amount,
(20 g calcium sulfate) x (34 grams ammonia / 74 g calcium sulfate)
= <em>9.19 g ammonia</em>
Answer,
For example, silver ion can be precipitated with hydrochloric acid to yield solid silver chloride. Because many cations will not react with hydrochloric acid in this way, this simple reaction can be used to separate ions that form insoluble chlorides from those that do not.