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liberstina [14]
4 years ago
15

Hydrogen iodide decomposes as 2Hl ----> H2 + I2. The average reaction rate is expressed as: Average rate - delta[HI]/delta, T

he negative sign used in the rate expression indicates that: a) There are repulsive forces between the reactants. b) The concentration of Hl decreases with time. c) The concentration of the reactants is less than that of the product d)) The reaction rate is decreasing with time
Chemistry
1 answer:
lara31 [8.8K]4 years ago
8 0

Answer: Option C. The concentration of the reactants is less than that of the product d

Explanation:

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A reaction has a rate constant of 2.08 × 10−4 s−1 at 26 oC and 0.394 s−1 at 79 oC . Determine the activation barrier for the rea
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<u>Explanation:</u>

To calculate activation energy of the reaction, we use Arrhenius equation, which is:

\ln(\frac{K_{79^oC}}{K_{26^oC}})=\frac{E_a}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

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K_{79^oC} = equilibrium constant at 79°C = 0.394s^{-1}

K_{26^oC} = equilibrium constant at 26°C = 2.08\times 10^{-4}s^{-1}

E_a = Activation energy of the reaction = ?

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = 26^oC=[26+273]K=299K

T_2 = final temperature = 79^oC=[79+273]K=352K

Putting values in above equation, we get:

\ln(\frac{0.394}{2.08\times 10^{-4}})=\frac{E_a}{8.314J/mol.K}[\frac{1}{299}-\frac{1}{352}]\\\\E_a=124595J/mol=124.6kJ/mol

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