1 kilo joule = 0.239006 calories
134 kilo joule = 134 x 0.239006
= 32.026804 calories
This problem is very easy to answer. You simply have to look at the subscripts of each element of the compound.
1. For caffeine, which has a molecular formula of C₈H₁₀N₄O₂, it contains 8 atoms of Carbon, 10 atoms of Hydrogen, 4 atoms of Nitrogen and 2 atoms of Oxygen.
2. For Iron(III) Sulfate, which has a molecular formula of Fe₂(SO₄)₃, it contains 2 atoms of Iron, 3 atoms of Sulfur, and 12 atoms of Oxygen.
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I would say it is a chemical change because after a while, the nails start to rust. Now they only rust after about a week though. But rust is a chemical change.