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Nady [450]
3 years ago
5

Predict whether the changes in enthalpy, entropy, and free energy will be positive or negative for the boiling of water, and exp

lain your predictions. How does temperature affect the spontaneity of this process?
Chemistry
1 answer:
Sedbober [7]3 years ago
4 0

Answer:

ΔH > 0; ΔS >0; ΔG = 0

Not spontaneous when T < 100 °C;

         Equilibrium when T = 100 °C

      Spontaneous when T > 100 °C

Step-by-step explanation:

The process is

H₂O(ℓ) ⇌ H₂O(g)

ΔH > 0 (positive), because we must <em>add heat</em> to boil water

ΔS > 0 (positive), because changing from a liquid to a gas i<em>ncreases the disorder </em>

ΔG = 0, because the liquid-vapour equilibrium process is at <em>equilibrium</em> at 100 °C

ΔG = ΔH – TΔS

Both ΔH and ΔS are positive.

If T = 100 °C, ΔG =0. ΔH = TΔS, and the system is at equilibrium.


If T < 100 °C, the ΔH term will predominate, because T has decreased below the equilibrium value.

ΔG > 0. The process is not spontaneous below 100 °C.


If T > 100 °C, the TΔS term will predominate, because T has increased above the equilibrium value.

ΔG < 0. The process is spontaneous above 100 °C.

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Answer:

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Explanation:

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a book with a mass of 1 kg is dropped from a height of 3 m. what is the potential energy of the book when it reaches the floor?
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PE=mgh
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5 0
3 years ago
Which aqueous solution has the highest boiling point at standard pressure?(1) 1.0 M KC1(aq) (3) 2.0 M KCl(aq)(2) 1.0 M CaC12(aq)
miss Akunina [59]

Answer:

(4) 2.0 M CaCl₂(aq).

Explanation:

  • Adding solute to water elevates the boiling point.
  • The elevation in boiling point (ΔTb) can be calculated using the relation:

<em>ΔTb = i.Kb.m,</em>

where, ΔTb is the elevation in boiling point.

i is the van 't Hoff factor.

  • van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass. For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1.

Kb is the molal elevation constant of water.

m is the molality of the solution.

<u><em>(1) 1.0 M KCl(aq):</em></u>

i for KCl = no. of particles produced when the substance is dissolved/no. of original particle = 2/1 = 2.

suppose molarity = molality, m = 1.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (2)(Kb)(1.0 m) = 2(Kb).

<u><em>(2) 2.0 M KCl(aq):</em></u>

i for KCl = no. of particles produced when the substance is dissolved/no. of original particle = 2/1 = 2.

suppose molarity = molality, m = 2.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (2)(Kb)(2.0 m) = 4(Kb).

<u><em>(3) 1.0 M CaCl₂(aq):</em></u>

i for CaCl₂ = no. of particles produced when the substance is dissolved/no. of original particle = 3/1 = 3.

suppose molarity = molality, m = 1.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (3)(Kb)(1.0 m) = 3(Kb).

<u><em>(4) 2.0 M CaCl₂(aq):</em></u>

i for CaCl₂ = no. of particles produced when the substance is dissolved/no. of original particle = 3/1 = 3.

suppose molarity = molality, m = 2.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (3)(Kb)(2.0 m) = 6(Kb).

  • <em>So, the aqueous solution has the highest boiling point at standard pressure is: (4) 2.0 M CaCl₂(aq).</em>

<em></em>

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