Answer:
Concentration of unknown solution is 0.0416 M
Explanation:
As we know
Absorbance is equal to the product of molar absorptivity of KMnO4 m, path length and concentration
From the given set of graphical data, it is clear that the absorbance vs concentration is a straight line.
From the graph, we can obtain-
Y = 5.73 X – 0.0065
Absorbance = 0.232
0.232 = 5.73 X – 0.0065
X = 0.0416
Concentration of unknown solution is 0.0416 M
MgH2 + 2 H2O → Mg(OH)2 + 2 H2
At the first reaction when 2HBr(g) ⇄ H2(g) + Br2(g)
So Kc = [H2] [Br2] / [HBr]^2
7.04X10^-2 = [H2][Br] / [HBr]^2
at the second reaction when 1/2 H2(g) + 1/2 Br2 (g) ⇄ HBr
Its Kc value will = [HBr] / [H2]^1/2*[Br2]^1/2
we will make the first formula of Kc upside down:
1/7.04X10^-2 = [HBr]^2/[H2][Br2]
and by taking the square root:
∴ √(1/7.04X10^-2)= [HBr] / [H2]^1/2*[Br]^1/2
∴ Kc for the second reaction = √(1/7.04X10^-2) = 3.769