Answer:
The reaction must be spontaneous, the disorder of the system increases.
Explanation:
By the Second Law of Thermodynamics, a positive change in entropy is due to a net input heat, and entropy is a measure of the grade of disorder within the system. The net input heat means that resultant goes to the system from the surroundings.
By the First Law of Thermodynamics, a net input heat is due to a positive change in enthalpy.
The reaction is endothermic and spontaneous (since change in entropy is positive).
In dilute solutions, the unit osmolarity is being used. It usually has units milliosmols per liter of solution or mOsmol/L. An osmole defines the number of moles of the solute that would have an effect on the osmotic pressure of the solution. Osmolarity is calculated by the product of the molarity and the number of particles in the solution which is 2 for potassium chloride. We calculate as follows:
Osmolarity = molarity (# of particles)250 mosmol/L ( 1 osmol / 1000 osmol) = x moles / .100 L (2)
x moles = 0.0125 mol KCl
mass KCl = 0.0125 mol KCl ( 39 + 35.5 g/mol) = 0.93125 g KCl
Diffusion is the process of a substance spreading out to evenly fill its container or environment. Rate of diffusion of a gas is inversely proportional to the molar mass of the gas.

Lighter(lower) the molar mass of the gas , faster will be its rate of diffusion and heavier (higher) the molar mass of the gas , slower will be its rate of diffusion.
We have to arrange the given gases from slowest rate of diffusion to fastest rate of diffusion that means we need to arrange gases from higher molar mass to lower molar mass.
Molar mass of given gases are :
Cl = 35.5 g/mol
Xe = 131.29 g/mol
He = 4.00 g/mol
N = 14.00 g/mol
So correct order for slowest rate of diffusion (highest molar mass) to fastest rate of diffusion (lowest molar mass) is :
Xe , Cl , N , He
Xe having the highest molar mass will have the slowest rate of diffusion and He with lowest molar mass will have the fastest rate of diffusion, so option 'c' is correct.
Note : Slowest rate of diffusion = High Molar Mass
Fastest rate of diffusion = Low Molar Mass