The information given in the diagram is the measure of two angles of each triangle.
We see that ∠B ≅ E and ∠A ≅ ∠E. Since we have two angles in both triangles congruent, by the AA postulate this says that the third angle in both triangles must be congruent as well.
Two triangles whose angle measures are the same are similar. However, they are not guaranteed to be congruent because they are similar; this is false.