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Irina18 [472]
3 years ago
7

Linolenic acid (C18H30O2) can be hydrogenated to stearic acid by reacting it with hydrogen gas according to the equation: C18H30

O2 + 3H2 --->C18H36O2 What volume of hydrogen gas, measured at STP, is required to react with 10.5 g of linolenic acid in this reaction?
Chemistry
1 answer:
Gnom [1K]3 years ago
6 0

1.998 ml of hydrogen gas volume is is required to react with 10.5 g of linolenic acid in this reaction.

Explanation:

Data given:

mass of linolenic acid is given = 10.5 grams

atomic mass of linoleinic acid = 278.43 grams/mole

volume of hydrogen required at STP = ?

Balance chemical reaction:

C18H30O2 + 3H2 --->C18H36O2

moles of linoleinic acid given  = \frac{mass}{atomic mass of 1 mole}

putting the values in the equation:

moles of linoleinic acid = \frac{10.5}{278.43}

                                      = 0.037 moles

from the balanced equation:

1 mole of linoleinic acid reacts with 3 moles of hydrogen

so, 0.037 moles will react with x moles of hydrogen gas

\frac{1}{3} = \frac{0.037}{x}

x = 0.111 moles of water

volume or mass = atomic mass x number of moles

volume of hydrogen gas= 1.998 ml

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Answer:

                     (a)  Theoretical Yield  =  10.50 g

                      (b)   %age yield  = 27.33 %

Explanation:

Answer-Part-(a)

                 The balance chemical equation for the synthesis of Ammonia is as follow;

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Step 1: Calculating moles of N₂ as;

                   Moles = Mass / M/Mass

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Step 2: Calculating moles of H₂ as;

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Step 3: Finding Limiting reagent as;

According to equation,

                1 mole of N₂ reacts with  =  3 moles of H₂

So,

             0.348 moles of N₂ will react with  =  X moles of H₂

Solving for X,

                     X = 3 mol × 0.348 mol / 1 mol

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It shows that to consume 0.348 moles of N₂ completely we require 1.044 mol of Hydrogen while, as given in statement we are only provided with 0.925 moles of H₂ hence, hydrogen  is limiting reagent. Therefore, H₂ will control the final yield.

Step 4: Calculating moles of Ammonia as,

According to equation,

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So,

             0.925 moles of H₂ will produce  =  X moles of NH₃

Solving for X,

                     X = 2 mol × 0.925 mol / 3 mol

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                     Theoretical Yield  =  Moles × M.Mass

                     Theoretical Yield  =  0.616 mol  × 17.03 g/mol

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                    %age yield  = 2.87 g / 10.50 g × 100

                    %age yield  = 27.33 %

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