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3 years ago

What volume of 0.205 M K3PO4 solution is necessary to completely react with 134 mL of 0.0102 M NiCl2?

1 answer:

5 0

the balanced equation for the above reaction is as follows;
3NiCl₂ + 2K₃PO₄ ---> Ni₃(PO₄)₂ + 6KCl
stoichiometry of NiCl₂ to K₃PO₄ is 3:2
the number of NiCl₂ moles reacted - 0.0102 mol/L x 0.134 L = 0.00137 mol
according to molar ratio
if 3 mol of NiCl₂ reacts with 2 mol of K₃PO₄
then 0.00137 mol of NiCl₂ reacts with - 2/3 x 0.00137 = 0.000911 mol of K₃PO₄

molarity of given K₃PO₄ solution - 0.205 M
there are 0.205 mol in 1000 mL
therefore volume of 0.000911 mol - 0.000911 mol / 0.205 mol/L = 4.44 mL
volume of K₃PO₄ needed is 4.44 mL

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Answer:

For A: The standard cell potential of the reaction is 4.4 V

For B: The standard Gibbs free energy of the reaction is $-8.50\times 10^5J$

For C: The reaction is spontaneous as written.

Explanation:

For A:

The given chemical reaction follows:

$2Li(s)+Cl_2(g)\rightarrow 2Li^+(aq.)+2Cl^-(aq.)$

The given half reaction follows:

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Here, chlorine will undergo reduction reaction will get reduced.

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the $E^o_{cell}$ of the reaction, we use the equation:

$E^o_{cell}=E^o_{cathode}-E^o_{anode}$

$E^o_{cell}=1.36-(-3.04)=4.4V$

Hence, the standard cell potential of the reaction is 4.4 V

For B:

Relationship between standard Gibbs free energy and standard electrode potential follows:

$\Delta G^o=-nFE^o_{cell}$

where,

n = number of electrons transferred = $2mol\text{ e}^-$

F = Faradays constant = $96500J/V.mol\text{ e}^-$

$E^o_{cell}$ = standard cell potential = 4.4 V

Putting values in above equation, we get:

$\Delta G^o=-2\times 96500\times 4.4=-849200J=-8.50\times 10^5J$

Hence, the standard Gibbs free energy of the reaction is $-8.50\times 10^5J$

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For a reaction to be spontaneous, the standard Gibbs free energy change of the reaction must be negative.

From above, the standard Gibbs free energy change of the reaction is coming out to be negative.

Hence, the reaction is spontaneous as written.

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3 years ago

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Answer:

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Explanation:

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3 years ago

Read 2 more answers

Enter your answer in the provided box.

Lina20 [59]

Answer:

5.06atm

Explanation:

Using the combined gas law equation;

P1V1/T1 = P2V2/T2

Where;

P1 = initial pressure (atm)

P2 = final pressure (atm)

V1 = initial volume (Litres)

V2 = final volume (Litres)

T1 = initial temperature (K)

T2 = final temperature (K)

According to the information provided in this question;

P1 = 1.34 atm

P2 = ?

V1 = 5.48 L

V2 = 1.32 L

T1 = 61 °C = 61 + 273 = 334K

T2 = 31 °C = 31 + 273 = 304K

Using P1V1/T1 = P2V2/T2

1.34 × 5.48/334 = P2 × 1.32/304

7.34/334 = 1.32P2/304

Cross multiply

334 × 1.32P2 = 304 × 7.34

440.88P2 = 2231.36

P2 = 2231.36/440.88

P2 = 5.06

The final pressure is 5.06atm

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Answer:

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