Draw the alkene formed when 1-heptyne is treated with hbr in the presence of peroxide.
1 answer:
<h2>Heptene formed is -</h2><h2>
</h2>
Explanation:
The two possibilities when the peroxide is not present
-
≡
→
+ HBr →
In presence peroxide,
≡
+ HBr →
- When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
- This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
- One mole of HBr adds to one mole of 1-heptane.
- The structure of heptene formed is -
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Answer: The value of for chloroform is
when 0.793 moles of solute in 0.758 kg changes the boiling point by 3.80 °C.
Explanation:
Given: Moles of solute = 0.793 mol
Mass of solvent = 0.758
As molality is the number of moles of solute present in kg of solvent. Hence, molality of given solution is calculated as follows.
Now, the values of is calculated as follows.
where,
i = Van't Hoff factor = 1 (for chloroform)
m = molality
= molal boiling point elevation constant
Substitute the values into above formula as follows.
Thus, we can conclude that the value of for chloroform is
when 0.793 moles of solute in 0.758 kg changes the boiling point by 3.80 °C.