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sertanlavr [38]
3 years ago
8

Draw the alkene formed when 1-heptyne is treated with hbr in the presence of peroxide.

Chemistry
1 answer:
Nimfa-mama [501]3 years ago
5 0
<h2>Heptene formed is -</h2><h2>CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr</h2>

Explanation:

The two possibilities when the peroxide is not present

  • CH_{3}-CH_{2}-CH_{2}-CH_{2}-CH_{2}-C≡CH +HBr → CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_{2}

  • CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_2 + HBr →CH_3-CH_2-CH_2-CH_2-CH_2-CBr_2-CH_3

In presence peroxide,

CH_3-CH_2-CH_2-CH_2-CH_2-C≡CH+ HBr →CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr

  • When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
  • This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
  • One mole of HBr adds to one mole of 1-heptane.
  • The structure of heptene formed is -

CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr

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Draw the structure(s) of the major organic product(s) of the following reaction. 1. lithium diisopropylamide / hexane 2. 1 eq. C
Jobisdone [24]

Answer:

See explanation below

Explanation:

You are not providing the starting material, however, I manage to find a similar question to this, so I'm gonna use it as a basis to help you answer yours.

Now let's analyze what is happening in the reaction so we can predict the final product.

We have a ketone here, reacting at first with LDA. This is a very strong base that is commonly used in reactions with ketones and aldehydes to promove a condensation. To do this, as LDA is a strong base it will occur firts an acid base reaction, substracting the most acidic hydrogen in the molecule (Which in this case, is the Beta hydrogen of the carbonile). This will cause an enolate formation.

Then, this enolate will react with the CH3I and form a new product. The final result would be a ketone with a methyl group now attached. In the picture 2, you have the mechanism and final product.

Hope this helps

6 0
3 years ago
How many moles in 843.211 grams of c6h12o6?
leonid [27]
Molar mass C6H12O6 = 12 x 6 + 1 x 12 + 16 x 6 = 180 g/mol

1 mole ------------ 180 g
( moles ) --------- 843.211 g

moles = 843.211 x 1 / 180

moles = 843.211 / 180

= 4,684 moles of C6H12O6
3 0
3 years ago
Why do deep earthquake do less damage then shallow ones ?
Nata [24]
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5 0
2 years ago
A compound such as CaCl, would have an overall charge of?
Rina8888 [55]

Calcium Chloride would have a charge of +2

Hopes this helps :)

7 0
3 years ago
10/24/14
vlabodo [156]

Answer:

d = Hydrogen and oxygen are being formed.

Explanation:

When current is passed through the water electrolysis take place.

Water is splitted into hydrogen and oxygen gas. Because of this formation bubbles are formed.

At cathode:

2H₂O + 2e⁻  → H₂ + 2OH⁻

Cathode is negatively charged and reduction take place on it.

At anode:

4OH⁻ → O₂ + 2H₂O + 4e⁻

Anode is positively charged and oxidation take place on it.

The over all reaction can be written as:

Chemical equation:

2H₂O  (electricity) →  2H₂  +  O₂

3 0
3 years ago
Read 2 more answers
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