Since the nucleophile is the actual attacking molecule or molecule that starts the reaction and allows for further steps in the mechanism to occur, it is the limiting reagent, as based on the amount of the nucleophile you have, the reaction will tend to proceed until you run out. The excess would be the sodium hydroxide, it is union part of the solution.
Chemical reaction (dissociation) 1: C₂O₄H₂(aq) ⇄ C₂O₄H⁻(aq) + H⁺(aq).
Chemical reaction (dissociation) 2: C₂O₄H⁻(aq) ⇄ C₂O₄²⁻(aq) + H⁺(aq).
c(C₂O₄H⁻) = c(H⁺) = x.
c(C₂O₄H₂) = 0.0269 M.
pKa₁ = 1.23.
Ka₁ = 10∧(-1.23) = 0.059.
Ka₁ = c(C₂O₄H⁻) · c(H⁺) / c(C₂O₄H₂).
0.059 = x² / (0.0269 M - x).
Solve quadratic eqaution: x = c(H⁺) = 0.02 M.
pH = -log(0.02 M) = 1.7.
Well, if u had a spilled liquid in there (we'll simply go with water) and you had the freezer at a cold temperature it would change (like,icycles on trees when it's snowing)
