Answer:
MECHANISM:
1) The lone pair on oxygen attacks the H-Br molecule forming a hydronium ion.
2) Formation of carbocation.
3) Attack of Nucleophile Br − .
Explanation:
Explanation:
According to the given data, we will calculate the following.
Half life of lipase 
= 8 min x 60 s/min
= 480 s
Rate constant for first order reaction is as follows.
= 
Initial fat concentration 
= 45 
= 45 mmol/L
Rate of hydrolysis 
= 0.07 mmol/L/s
Conversion X = 0.80
Final concentration (S) = 
= 45 (1 - 0.80)
= 9
or, = 9 mmol/L
It is given that 
= 5mmol/L
Therefore, time taken will be calculated as follows.
t = ![-\frac{1}{K_{d}}ln[1 - \frac{K_{d}}{V}{K_{M} ln (\frac{S_{o}}{S}) + (S_{o} - S)]](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7BK_%7Bd%7D%7Dln%5B1%20-%20%5Cfrac%7BK_%7Bd%7D%7D%7BV%7D%7BK_%7BM%7D%20ln%20%28%5Cfrac%7BS_%7Bo%7D%7D%7BS%7D%29%20%2B%20%28S_%7Bo%7D%20-%20S%29%5D)
Now, putting the given values into the above formula as follows.
t =
= ![-\frac{1}{1.44 \times 10^{-3}s^{-1}}ln[1 - \frac{1.44 \times 10^{-3}s^{-1}}{0.07 mmol/L/s }{K_{M} ln (\frac{45 mmol/L }{9 mmol/L }) + (45 mmol/L - 9 mmol/L )]](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B1.44%20%5Ctimes%2010%5E%7B-3%7Ds%5E%7B-1%7D%7Dln%5B1%20-%20%5Cfrac%7B1.44%20%5Ctimes%2010%5E%7B-3%7Ds%5E%7B-1%7D%7D%7B0.07%20mmol%2FL%2Fs%0A%7D%7BK_%7BM%7D%20ln%20%28%5Cfrac%7B45%20mmol%2FL%0A%7D%7B9%20mmol%2FL%0A%7D%29%20%2B%20%2845%20mmol%2FL%20-%209%20mmol%2FL%0A%29%5D)
= 
= 27.38 min
Therefore, we can conclude that time taken by the enzyme to hydrolyse 80% of the fat present is 27.38 min.
I believe that the answer is 11.5
Answer:
Explanation:
<u>1) First law of thermodynamic (energy balance)</u>
- Heat released by the the hot water (345K ) = Heat absorbedby the cold water (298 K) + Heat absorbed by the calorimeter
<u>2) Energy change of each substance:</u>
Heat released or absorbed = mass × Specific heat × change in temperature
- density of water: you may take 0.997 g/ ml as an average density for the water.
- mass of water: mass = density × volume = 50.0 ml × 0.997 g/ml = 49.9 g
- Specif heat of water: 1 cal / g°C
- Heat released by the hot water:
Heat₁ = 49.9 g × 1 cal / g°C × (345 K - 317 K) = 49.9 g × 1 cal / g°C × (28K)
- Heat absorbed by the cold water:
Heat₂ = 49.9 g × 1 cal / g°C × (317 K - 298 K) = 49.9 g × 1 cal / g°C × (19K)
- Heat absorbed by the calorimeter
Heat₃ = Ccal × (317 K - 298 K) = Ccal × (19K)
<u>4) Balance</u>
49.9 g × 1 cal / g°C × (28 K) = 49.9 g × 1 cal / g°C × (19 K) + Ccal × (19 K)
Ccal = [49.9 g × 1 cal / g°C × (28 K) - 49.9 g × 1 cal / g°C × (19 K) ] / 19K
Ccal = 23.6 cal/ K
- Convert to cal / K to Joule / K
23.6 cal / K × 4.18 J / cal = 98.6 J/K
Which rounded to 2 signficant figures leads to 99 J/k, which is the first choice.
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