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sdas [7]
3 years ago
14

In going from room temperature (25 C) to 10 C above room temperature, the rate of reaction doubles. Calculate the activation ene

rgy for the reaction .
Chemistry
1 answer:
Sauron [17]3 years ago
8 0

Answer:

Ea=5.29 × 10⁴ J/mol

Explanation:

In going from 25 °C (298 K) to 35 °C (308 K), the rate of the reaction doubles. Since the rate of the reaction depends on the rate constant (k), this implies that the rate constant doubles. We can find the activation energy (Ea) using the two-point form of the Arrhenius equation.

ln\frac{k_{2}}{k_{1}} =\frac{-Ea}{R} .(\frac{1}{T_{2}}-\frac{1}{T_{1}})\\ln\frac{2k_{1}}{k_{1}}=\frac{-Ea}{8.314J/K.mol}.(\frac{1}{308K}-\frac{1}{298K} )\\Ea=5.29 \times 10^{4} J/mol

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Answer:

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Explanation:

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3 0
3 years ago
What mass of nitrous oxide gas (N2O) is contained in 20.0 L balloon at a pressure of 110.0 kPa and a temperature of 25 C?
likoan [24]

Answer:

40.94 g

Explanation:

Given data:

Mass of NO₂ = ?

Volume = 20.0 L

Pressure = 110.0 Pka

Temperature = 25°C

Solution:

Pressure = 110.0 KPa (110/101 = 1.1 atm)

Temperature = 25°C (25+273 = 298.15 K)

The given problem will be solve by using general gas equation,

PV = nRT

P= Pressure

V = volume

n = number of moles

R = general gas constant = 0.0821 atm.L/ mol.K  

T = temperature in kelvin

n = PV/RT

n = 1.1 atm × 20.0 L / 0.0821 atm.L/ mol.K ×298.15 K

n = 22 / 24.5 /mol

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Mass = number of moles × molar mass

Mass = 0.89 mol × 46 g/mol

Mass = 40.94 g

3 0
3 years ago
KFell Fe"(CN), + e + Nat → KNaFe'Fe(CN)6
Alinara [238K]

Answer:

Most common oxidation states: +2, +3

M.P. 1535º

B.P. 2750º

Density 7.87 g/cm3

Characteristics: Iron is a gray, moderately active metal.

Characteristic reactions of Fe²⁺ and Fe³⁺

The [Fe(H2O)6]3+ ion is colorless (or pale pink), but many solutions containing this ion are yellow or amber-colored because of hydrolysis. Iron in both oxidation states forms many complex ions.

Aqueous Ammonia

Aqueous ammonia reacts with Fe(II) ions to produce white gelatinous Fe(OH)2, which oxidizes to form red-brown Fe(OH)3:

Fe2+(aq)+2NH3(aq)+3H2O(l)↽−−⇀Fe(OH)2(s)+2NH+4(aq)(1)

Fe3appt.gif

Aqueous ammonia reacts with Fe(III) ions to produce red-brown Fe(OH)3:

Fe3+(aq)+3NH3(aq)+3H2O(l)↽−−⇀Fe(OH)3(s)+3NH+4(aq)(2)

Fe3bppt.gif

Both precipitates are insoluble in excess aqueous ammonia. Iron(II) hydroxide quickly oxidizes to Fe(OH)3 in the presence of air or other oxidizing agents.

Sodium Hydroxide

Sodium hydroxide also produces Fe(OH)2 and Fe(OH)3 from the corresponding oxidation states of iron in aqueous solution.

Fe2+(aq)+2OH−(aq)↽−−⇀Fe(OH)2(s)(3)

Fe4appt.gif

Fe3+(aq)+3OH−(aq)↽−−⇀Fe(OH)3(s)(4)

Fe4bppt.gif

Neither hydroxide precipitate dissolves in excess sodium hydroxide.

Potassium Ferrocyanide

Potassium ferrocyanide will react with Fe3+ solution to produce a dark blue precipitate called Prussian blue:

K+(aq)+Fe3+(aq)+[Fe(CN)6]4−(aq)↽−−⇀KFe[Fe(CN)6](s)(5)

Fe5a1ppt.gif

With Fe2+ solution, a white precipitate will be formed that will be converted to blue due to the oxidation by oxygen in air:

2Fe2+(aq)+[Fe(CN)6]4−(aq)↽−−⇀Fe2[Fe(CN)6](s)(6)

Fe5a2ppt.gif

Many metal ions form ferrocyanide precipitates, so potassium ferrocyanide is not a good reagent for separating metal ions. It is used more commonly as a confirmatory test.

Potassium Ferricyanide

Potassium ferricyanide will give a brown coloration but no precipitate with Fe3+. With Fe2+, a dark blue precipitate is formed. Although this precipitate is known as Turnbull's blue, it is identical with Prussian blue (from Equation 5).

K+(aq)+Fe+2(aq)+[Fe(CN)6]3−(aq)↽−−⇀KFe[Fe(CN)6](s)(7)

Fe5b.gif

Potassium Thiocyanate

KSCN will give a deep red coloration to solutions containing Fe3+:

Fe+3(aq)+NCS−(aq)↽−−⇀[FeNCS]+2(aq)(8)

Fe5cppt.gif

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3 years ago
Brownian motion is not observed in a mixture that includes two phases. Which best identifies the mixture? [A} a colloid
Hoochie [10]

b, a suspension

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3 0
3 years ago
True or False: It is OK to use wet glassware for the aspirin synthesis without potentially affecting your yield
vesna_86 [32]

Answer:

False

Explanation:

Laboratory synthesis of aspirin is done by the acetylation of salicylic acid with the help of acetic anhydride .

As , the  acid anhydride is very sensitive to moisture , as it can hydrolyze into two molecules of  acids,

Hence , the reaction involving acid anhydride  are conducted in anhydrous solvents .

Hence ,

if water is  present in the glassware then , some of the acetic anhydride is wasted , Which in turns reduces the yield than that expected .

5 0
3 years ago
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