Answer: If you think about it, B. would be the most reasonable answer with the given factors.
CH4 : H2O
1 : 2
number of moles of H2O = 1.00 x 2
number of moles of H2O = 2.00mol
mass = number of moles x molar mass
mass of H2O = 2.00 x (1 + 1 + 16)
mass of H2O = 36g
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer:
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Explanation:
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Answer:
b. CH₂Cl₂ is more volatile than CH₂Br₂ because of the large dispersion forces in CH₂Br₂
Explanation:
CH₂Cl₂ is more volatile than CH₂Br₂ (b.p of CH₂Cl₂ = 39,6 °C; b.p of CH₂Br₂ = 96,95°C). Thus, c. and d. are FALSE
Dipole-dipole interactions in CH₂Cl₂ are greater than the dipole-dipole interactions in CH₂Br₂ because Cl is more electronegative that Br (Cl = 3,16; Br = 2,96). But this mean CH₂Cl₂ is less volatile than CH₂Br₂ but it is false.
There are large dispersion forces in CH₂Br₂ because Br has more electrons and protons than Cl. Large disperson forces mean CH₂Br₂ is less volatile than CH₂Cl₂ and it is true.
I hope it helps!
