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Evgesh-ka [11]
3 years ago
5

Nitrogen dioxide and water react to form nitric acid and nitrogen monoxide, like this:

Chemistry
1 answer:
posledela3 years ago
5 0

Answer: The value of the equilibrium constant Kc for this reaction is 3.72

Explanation:

Equilibrium concentration of HNO_3 = \frac{15.5g}{63g/mol\times 9.5L}=0.026M

Equilibrium concentration of NO = \frac{16.6g}{30g/mol\times 9.5L}=0.058M

Equilibrium concentration of NO_2 = \frac{22.5g}{46g/mol\times 9.5L}=0.051M

Equilibrium concentration of H_2O = \frac{189.0g}{18g/mol\times 9.5L}=1.10M

Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as K_c  

For the given chemical reaction:

2HNO_3(aq)+NO(g)\rightarrow 3NO_2(g)+H_2O(l)

The expression for K_c is written as:

K_c=\frac{[NO_2]^3\times [H_2O]^1}{[HNO_3]^2\times [NO]^1}

K_c=\frac{(0.051)^3\times (1.10)^1}{(0.026)^2\times (0.058)^1}

K_c=3.72

Thus  the value of the equilibrium constant Kc for this reaction is 3.72

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8 0
3 years ago
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From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp
Nina [5.8K]

<u>Answer:</u> The concentration of NH_3 required will be 0.285 M.

<u>Explanation:</u>

To calculate the molarity of NiC_2O_4, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Moles of NiC_2O_4 = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M

For the given chemical equations:

NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}

Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9

Net equation: NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?

To calculate the equilibrium constant, K for above equation, we get:

K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48

The expression for equilibrium constant of above equation is:

K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}

As, NiC_2O_4 is a solid, so its activity is taken as 1 and so for C_2O_4^{2-}

We are given:

[[Ni(NH_3)_6]^{2+}]=0.016M

Putting values in above equations, we get:

0.48=\frac{0.016}{[NH_3]^6}}

[NH_3]=0.285M

Hence, the concentration of NH_3 required will be 0.285 M.

7 0
3 years ago
WILL MARK BRANILEST
ahrayia [7]

Answer:

FeCl3 is the limiting reactant

O2 is in excess

Theoretical yield Cl2 = 9.84 grams

The % yield is 96.5 %

Explanation:

Step 1: Data given

Mass of FeCl3 = 15.0 grams

Moles O2 = 4.0 moles

Mass of Cl2 produced = 9.5 grams

Step 2: The balanced equation

4FeCl3 + 3O2 → 2Fe2O3 + 6Cl2

Step 3: Calculate moles FeCl3

Moles FeCl3 = mass FeCl3 / molar mass FeCl3

Moles FeCl3 = 15.0 grams / 162.2 g/mol

Moles FeCl3 = 0.0925 moles

Step 4: Calculate limiting reactant

FeCl3 is the limiting reactant. Because we have way more (more than ratio 3:4) moles O2 than FeCl3. It will completely be consumed (0.0925 moles). O2 is in excess. There will react = 0.069375 moles O2

There will remain 4.0 - 0.069375 = 3.930625 moles

Step 5: Calculate moles Cl2

For 4 moles FeCl3 we need 3 moles O2 to produce 2 moles Fe2O3 and 6 moles Cl2

For 0.0925 moles FeCl3 moles we'll have 6/4 * 0.0925 = 0.13875 moles Cl2.

Step 6: Calculate mass Cl2

Mass Cl2 = moles * molar mass

Mass Cl2 = 0.13875 moles * 70.9 g/mol

Mass Cl2 = 9.84 grams

Step 7: Calculate % yield

% yield = (actual yield / theoretical yield) * 100%

% yield = (9.5 grams / 9.84 grams ) * 100%

% yield = 96.5 %

The % yield is 96.5 %

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Answer:

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Explanation:

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