4.1 h = 14760 s
<span>t 1/2 = ln 2 / k </span>
<span>k = rate reaction = 4.97 x 10^-5 </span>
<span>ln 0.045 / 0.36 = - 4.97 x 10^-5 t </span>
<span>2.08 = 4.97 x 10^-5 t </span>
<span>t = 41839.9 s = 11 h 37 min 19 s</span>
Noble gases.
group 18. elements that are all unreactive .
fixed naming!
Answer is: concentration of hydrogenium ions is 9,54·10⁻⁵ M.
c(HNO₂) = 0,075 M.
c(NaNO₂) = 0,035 M.
Ka(HNO₂) = 4,5·10⁻⁵.
This is buffer solution, so use <span>Henderson–Hasselbalch equation:
pH = pKa + log(c(</span>NaNO₂) ÷ c(HNO₂)).
pH = -log(4,5·10⁻⁵) + log(0,035 M ÷ 0,075 M).
pH = 4,35 - 0,33.
pH = 4,02.
<span>[H</span>₃O⁺] = 10∧(-4,02).
<span>[H</span>₃O⁺] = 0,0000954 M = 9,54·10⁻⁵ M.
If 1000 ml (1 L) of CH₃COOH contain 1.25 mol
let 250 ml of CH₃COOH contain x
⇒ x =
= 0.3125 mol
∴ moles of CH₃COOH in 250ml is 0.3125 mol
Now, Mass = mole × molar mass
= 0.3125 mol × [(12 × 2)+(16 × 2)+(1 × 4)] g/mol
= 18.75 g
∴ Mass of CH₃COOH present in a 250 mL cup of 1.25 mol/L solution of vinegar is <span>18.75 g</span>