Type this into your calculator (1/52)×(25/51) then convert to a percentage or fraction of leave as a decimal if that's what it asks for.
There is only 1 ace of clubs and it is black, so the first probability is 1/52. One ace of clubs out of 52 total cards.
Next, you keep the first pick and want a black card second. You subtract the one card you took from the total deck, leaving you with 51. (btw With replacement, you would simply keep the total as 52) There are 26 red cards and 26 black cards in a deck. It would be 26/52, but since the ace of clubs is black, it is 25/51.
Finally, you multiply both probabilities to get the overall probability (lol weird way of saying that, but I hope you get what I mean).