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3 years ago

A gas has a pressure of 1.34 atm when the temperature is 237K. The gas is then

Chemistry

1 answer:

Naddika [18.5K]3 years ago

6 0

Answer:

$\large \boxed{\text{1.76 atm}}$

Explanation:

The volume and amount of gas are constant, so we can use Gay-Lussac’s Law:

At constant volume, the pressure exerted by a gas is directly proportional to its temperature.

$\dfrac{p_{1}}{T_{1}} = \dfrac{p_{2}}{T_{2}}$

Data:

p₁ = 1.34 atm; T₁ = 237 K

p₂ = ?; T₂ = 312 K

Calculations:

$\begin{array}{rcl}\dfrac{1.34}{237} & = & \dfrac{p_{2}}{312}\\\\5.654 \times 10^{-3} & = & \dfrac{p_{2}}{312}\\\\5.654 \times 10^{-3}\times312&=&p_{2}\\p_{2} & = & \textbf{1.76 atm}\end{array}\\\text{The new pressure will be $\large \boxed{\textbf{1.76 atm}}$}$

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78.6 grams of O2 and 67.3 grams of F2 are placed in a container with a volume of 40.6 L. Find the total pressure if the gasses a

saul85 [17]

1) List the known and unknown quantities.

Sample: O2.

Mass: 78.6 g.

Volume: 40.6 L.

Temperature: 43.13 ºC = 316.28 K.

Sample: F2.

Mass: 67.3 g.

Volume: 40.6 L.

Temperature: 43.13 ºC = 316.28 K.

2) Find the pressure of O2.

2.1- List the known and unknown quantities.

Sample: O2.

Mass: 78.6 g.

Volume: 40.6 L.

Temperature: 43.13 ºC = 316.28 K

Ideal gas constant: 0.082057 L * atm * K^(-1) * mol^(-1).

2.2- Convert grams of O2 to moles of O2.

The molar mass of O2 is 31.9988 g/mol.

$mol\text{ }O_2=78.6\text{ }g*\frac{1\text{ }mol\text{ }O_2}{31.9988\text{ }g\text{ }O_2}=2.46\text{ }mol\text{ }O_2$

2.3- Set the equation.

Ideal gas constant: 0.082057 L * atm * K^(-1) * mol^(-1)

$PV=nRT$

2.4- Plug in the known quantities and solve for P.

$(P)(40.6\text{ }L)=(2.46\text{ }mol\text{ }O_2)(0.082057\text{ }L*atm*K^{-1}*mol^{-1})(316.28\text{ }K)$

.

$P_{O_2}=\frac{(2.46\text{ }mol\text{ }O_2)(0.082057\text{ }L*atm*K^{-1}*mol^{-1})(316.28\text{ }K)}{40.6\text{ }L}$ $P_{O_2}=1.57\text{ }atm$

The pressure of O2 is 1.57 atm.

3) Find the pressure of F2.

3.1- List the known and unknown quantities.

Sample: F2.

Mass: 67.3 g.

Volume: 40.6 L.

Temperature: 43.13 ºC = 316.28 K.

Ideal gas constant: 0.082057 L * atm * K^(-1) * mol^(-1).

3.2- Convert grams of F2 to moles of F2.

The mmolar mass of F2 is 37.9968 g/mol.

$mol\text{ }F_2=67.3\text{ }g\text{ }F_2*\frac{1\text{ }mol\text{ }F_2}{37.9968\text{ }g\text{ }F_2}=1.77\text{ }mol\text{ }F_2$

3.3- Set the equation.

Ideal gas constant: 0.082057 L * atm * K^(-1) * mol^(-1)

$PV=nRT$

3.4- Plug in the known quantities and solve for P.

$(P)(40.6\text{ }L)=(1.77\text{ }mol\text{ }F_2)(0.082057\text{ }L*atm*K^{-1}*mol^{-1})(316.28\text{ }K)$

.

$P_{F_2}=\frac{(1.77molF_2)(0.082057L*atm*K^{-1}*mol^{-1})(316.28K)}{40.6\text{ }L}$ $P_{F_2}=1.13\text{ }atm$

The pressure of F2 is 1.13 atm.

4) The total pressure.

Dalton's law - Partial pressure. This law states that the total pressure of a gas is equal to the sum of the individual partial pressures.

4.1- Set the equation.

$P_T=P_A+P_B$

4.2- Plug in the known quantities.

$P_T=1.57\text{ }atm+1.13\text{ }atm$ $P_T=2.7\text{ }atm$

The total pressure in the container is 2.7 atm.

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1 year ago

Give the major product formed when phenol is heated with concentrated H2SO4 and SO3. (There is more than one correct answer, but

iris [78.8K]

Answer:

See image attached and explanation

Explanation:

The reaction of phenol with SO3/H2SO4 is an electrophilic reaction. The electrophile attacks portions of high electron density in the substrate phenol.

The -OH group activates phenol towards electrophilic substitution at the ortho and para positions, hence the product(s) formed in this reaction(only one product is shown here as required by the question).

The sulphonation of phenol using concentrated sulfuric acid at lower temperature yields majorly the ortho product whereas at higher temperature the para product predominates.

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3 years ago

Given the following chemical reaction: 2 O2 + CH4 --> CO2 + 2 H2O

Elis [28]

The answer is D) 144 grams O2

5 0

4 years ago

Read 2 more answers

The initial volume of HCl was 1.25 ml and LiOH was 2.65 ml. The final volume of HCL was 13.60 ml and LiOH was 11.20 ml. If the L

Dennis_Churaev [7]

Q1)
This is a strong acid- strong base base reaction, balanced equation for the reaction is as follows;
LiOH + HCl ---> LiCl + H₂O
stoichiometry of acid to base is 1:1
volume of HCl used up - 13.60 - 1.25 = 12.35 mL
volume of LiOH used up - 11.20 - 2.65 = 8.55 mL
molarity of LiOH - 0.140 M
The number of LiOH moles reacted - $\frac{0.140 mol/L*8.55mL}{1000mL}$ = 0.001197 mol
according to stoichiometry, number of LiOH moles = number of HCl moles
Therefore number of HCl moles reacted - 0.001197 mol
The number of HCl moles in 12.35 mL - 0.001197 mol
Then number of HCl moles in 1000 mL - $\frac{0.001197*1000mL}{12.35mL}$
Molarity of HCl - 0.0969 M

Q2)
Volume of HCl used - 12.35 mL
Volume of LiOH used - 8.55 mL
Molarity of HCl - 0.140 M
In 1 L solution of HCl there are 0.140 mol of HCl
Therefore number of HCl moles in 12.35 mL - $\frac{0.140mol*12.35 mL}{1000mL}$
Number of HCl moles reacted - 0.001729 mol
since molar ratio of acid to base is 1:1
the number of LiOH moles that reacted - 0.001729 mol
Therefore number of moles in 8.55 mL - 0.001729
Then number of LiOH moles in 1000 mL - $\frac{0.001729mol*1000mL}{8.55 mL}$
molarity of LiOH - 0.202 M

5 0

3 years ago

Consider the following half-reactions and their standard reduction potential values to answer the following questions.

Ganezh [65]

Answer:

Br2 (l) + 2e- ---------> 2Br- (aq) E° = 1.08 V cathode

Cu2+ (aq) + e- --------->Cu+ (aq) E° = 0.15 V anode

Explanation:

We have to first state the fact that the reaction having the most positive reduction potential occurs at the cathode in any spontaneous electrochemical cell. The half reaction with the less positive electrode potential usually occurs at the anode.

The overall reaction equation is;

2Cu2+ (aq) + Br2 (l) ----->2Cu+ (aq) + 2Br- (aq)

E°cell= E°cathode - E°anode

E°cathode= 1.08 V

E°anode= 0.15V

E°cell = 1.08-0.15 = 0.93 V

But

∆G°= -nFE°cell

n= 2, F=96500C, E°cell= 0.93V

∆G° = -(2× 96500× 0.93)

∆G= -179490 J

But;

∆G = -RTlnK

R=8.314 JK-1

T= 25+273= 298K

Kc= the unknown

∆G° = -179490 J

Substituting values and making lnK the subject of the formula

lnK= ∆G/-RT

lnK= -( -179490/8.314 × 298)

lnK= 72.45

K= e^72.45

K= 2.91×10^31

4 0

3 years ago