Given the following chemical reaction: 2 O2 + CH4 --> CO2 + 2 H2O
2 answers:
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Complete Question
The complete question is shown on the first uploaded image
Answer:
a) Splitting pattern for Ha= 2+1 , Triplet
For Proton Hb and Hc both are equivalent to each other. non equivalent protons n= 3
Splitting pattern for Hb and Hc= 3+1 , Quartet
For Proton Hd, number of non equivalent protons n= 0
Splitting pattern for Hd= 0+1 , Singlet
b) Splitting pattern for Ha= 2+1 , Triplet
For Proton Hb and Hc both are equivalent to each other. non equivalent protons n= 3
Splitting pattern for Hb and Hc= 3+1 , Quartet
For Proton Hd, number of non equivalent protons n= 0
Splitting pattern for Hd= 0+1 , Singlet
c) The IUPAC name is Butan-2-ol
Explanation:
Considering the first question the rule used for prediction of splitting pattern is n+1 (Pascal's Triangle rule), where n is number of H atom on the adjacent carbon which are non equivalent.
According to that for molecule 1 as shown on the second uploaded image
For Proton Ha, number of non equivalent protons n= 2
Splitting pattern for Ha= 2+1 , Triplet
For Proton Hb and Hc both are equivalent to each other. non equivalent protons n= 3
Splitting pattern for Hb and Hc= 3+1 , Quartet
For Proton Hd, number of non equivalent protons n= 0
Splitting pattern for Hd= 0+1 , Singlet
Considering the second question for Molecule 2 as shown on the third uploaded image
For Proton Ha, number of non equivalent protons n= 1
Splitting pattern for Ha= 1+1=2 , Doublet
For Proton Hb, number of non equivalent protons n= 3
Splitting pattern for Hb= 3+1=4 , Quartet
For Proton Hc, number of non equivalent protons n= 3
Splitting pattern for Hc= 3+1=4 , Quartet
For Proton Hd, number of non equivalent protons n= 1
Splitting pattern for Ha= 1+1=2 , Doublet
Considering the third question
The name of the given molecule is gotten according to longest carbon chain = 4 (Prefix 'Butan')
Functional group = -OH (Suffix 'ol') at C-2
The IUPAC name is Butan-2-ol
Answer:
a. Cyclohexanone
Explanation:
The principle of IR technique is based on the <u>vibration of the bonds</u> by using the energy that is in this region of the electromagnetic spectrum. For each bond, there is <em>a specific energy that generates a specific vibration</em>. In this case, you want to study the vibration that is given in the carbonyl group C=O. Which is located around 1700 cm-1.
Now, we must remember that the <u>lower the wavenumber we will have less energy</u>. So, what we should look for in these molecules, is a carbonyl group in which less energy is needed to vibrate since we look for the molecule with a smaller wavenumber.
If we look at the structure of all the molecules we will find that in the last three we have <u>heteroatoms</u> (atoms different to carbon I hydrogen) on the right side of the carbonyl group. These atoms allow the production of <u>resonance structures</u> which makes the molecule more stable. If the molecule is more stable we will need more energy to make it vibrate and therefore greater wavenumbers.
The molecule that fulfills this condition is the <u>cyclohexanone.</u>
See figure 1
I hope it helps!
