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fiasKO [112]
3 years ago
9

Consider the reaction: 2 HCl(aq) + Ba(OH)2(aq) BaCl2(aq) + 2 H2O(l); H = –118 kJ. Calculate the change in temperature when 50.

0 mL of 0.20 M HCl(aq) and 50.0 mL of 0.10 M Ba(OH)2(aq) are mixed together. The density ofthe solution is 1.00 g/mL and Solution= 4.184 J/g-°C
Chemistry
1 answer:
Alborosie3 years ago
6 0

Answer:

ΔT = 1,41°C

Explanation:

For the reaction:

2HCl(aq) + Ba(OH)₂(aq) → BaCl₂(aq) + 2 H₂O(l); ΔH = –118 kJ.

If moles of reaction are:

HCl:

0,0500L×0,20M = 0,01moles

Ba(OH)₂:

0,0500L×0,10M = 0,005moles

The heat produced is:

0,005mol×-118 kJ/mol = -0,59 kJ = -590 J

The temperature increasing is:

Q = -C×m×ΔT

Where Q is heat (-590 J), m is mass of solution (100mL = 100g -density of 1,00g/mL) and ΔT is change in temperature.

Replacing:

-590J = -4,184J/g°C×100g×ΔT

<em>ΔT = 1,41°C</em>

<em></em>

I hope it helps!

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Consider the following reaction of the commercial production of SO3 using sulfur dioxide and oxygen: ​ SO2(g) + O2(g) → SO3(g) ​
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Answer:

m_{SO_3}=18.93gSO_3

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STP conditions are P=1 atm and T=273.15 K, thus, the reacting moles are:

n_{SO_2}=\frac{5.3L*1atm}{0.082\frac{atm*L}{mol*K}*273.15K}=0.2366molSO_2\\n_{O_2}=\frac{4.7L*1atm}{0.082\frac{atm*L}{mol*K}*273.15K}=0.2098molO_2

Now, the balanced chemical reaction turns out into:

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Thus, the exact moles of oxygen that completely react with 0.2366 moles of sulfur dioxide are (limiting reagent identification):

0.2366molSO_2*\frac{1molO_2}{2molSO_2}=0.1182molO_2

Since 0.2098 moles of oxygen are available, we stipulate the oxygen is in excess and the sulfur dioxide is the limiting reagent. In such a way, the yielded grams of sulfur trioxide turn out into:

m_{SO_3}=0.2366molSO_2*\frac{2molSO_3}{2molSO_2}*\frac{80gSO_3}{1molSO_3} \\m_{SO_3}=18.93gSO_3

By using the ideal gas equation, one computes the volume as:

V_{SO_3}=\frac{mRT}{MP}=\frac{18.93g*0.082\frac{atm*L}{mol*K} *273.15K}{80g/mol*1atm}\\V_{SO_3}=5.3LSO_3

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Best regards.

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The molar ratio of RCOOH to NaOH is 1:1. The moles of RCOOH are:

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