Answer:
20ppm
Explanation:
parts per million are defined as the mass of solute in mg (In this case, mass of DDT) per kg of sample.
To solve this question we must find the mass of DDT in mg and the mass of sample in kg:
<em>Mass DDT:</em>
0.10g * (1000mg / 1g) = 100mg
<em>Mass sample:</em>
5000g * (1kg / 1000g) = 5kg
Parts per Million:
100mg / 5kg =
<h3>20ppm</h3>
since the concentration of Carbon Dioxide will increase, it would make Q > K, cause equilibrium to shift in the direction with less moles of gas to alleviate the extra pressure. In this case, the reaction will shift left because there are fewer moles of gas present.
Answer:
Enthalpy change for the reaction is -67716 J/mol.
Explanation:
Number of moles of
in 50.0 mL of 0.100 M of 
= Number of moles of HCl in 50.0 mL of 0.100 M of HCl
=
moles
= 0.00500 moles
According to balanced equation, 1 mol of
reacts with 1 mol of HCl to form 1 mol of AgCl.
So, 0.00500 moles of
react with 0.00500 moles of HCl to form 0.00500 moles of AgCl
Total volume of solution = (50.0+50.0) mL = 100.0 mL
So, mass of solution = (
) g = 100 g
Enthalpy change for the reaction = -(heat released during reaction)/(number of moles of AgCl formed)
=
= ![\frac{-100g\times 4.18\frac{J}{g.^{0}\textrm{C}}\times [24.21-23.40]^{0}\textrm{C}}{0.00500mol}](https://tex.z-dn.net/?f=%5Cfrac%7B-100g%5Ctimes%204.18%5Cfrac%7BJ%7D%7Bg.%5E%7B0%7D%5Ctextrm%7BC%7D%7D%5Ctimes%20%5B24.21-23.40%5D%5E%7B0%7D%5Ctextrm%7BC%7D%7D%7B0.00500mol%7D)
= -67716 J/mol
[m = mass, c = specific heat capacity,
= change in temperature and negative sign is included as it is an exothermic reaction]
NaOH reacts with CH3COOH in 1:1 molar ratio to produce CH3COONa
NaOH + CH3COOH → CH3COONa + H2O
Mol CH3COOH in 52.0mL of 0.35M solution = 52.0/1000*0.35 = 0.0182 mol CH3COOH
Mol NaOH in 19.0mL of 0.40M solution = 19.0/1000*0.40 = 0.0076 mol NaOH
These will react to produce 0.0076 mol CH3COONa and there will be 0.0182 - 0.0076 = 0.0106 mol CH3COOH remaining in solution unreacted . Total volume of solution = 52.0+19.0 = 71mL or 0.071L
Molarity of CH3COOH = 0.0106/0.071 = 0.1493M
CH3COONa = 0.0076 / 0.071 = 0.1070M
pKa acetic acid = - log Ka = -log 1.8*10^-5 = 4.74.
pH using Henderson - Hasselbalch equation:
pH = pKa + log ([salt]/[acid])
pH = 4.74 + log ( 0.1070/0.1493)
pH = 4.74 + log 0.717
pH = 4.74 + (-0.14)
pH = 4.60.