100,000 years ago is your answer
A food chain follows one path of energy and materials between species. A food web is more complex and is a whole system of connected food chains. In a food web, organisms are placed into different trophic levels. ... Producers are the basic trophic level while top predators are the peak level.
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Enzymes are biological catalysts. Catalysts lower the activation energy for reactions. The lower the activation energy for a reaction, the faster the rate. Thus enzymes speed up reactions by lowering activation energy.