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laiz [17]
3 years ago
15

Calculate the change in entropy when 1.00 kg of water at 100 degree C is vaporized and converted to steam at 100 degree C. Assum

e that the heat of vaporization of water is 2256 Times 103 J/kg. Calculate the change in entropy when 1.00 kg of ice is melted at 0 degree C. Assume that the heat of fusion of water is Lf = 3.34 Times 105J/kg. Is the change entropy greater for melting or for vaporization? the change entropy greater for melting the change entropy greater for vaporization
Physics
1 answer:
dexar [7]3 years ago
4 0

Answer:

Case 1 : Entropy of vaporization of water is \Delta S=6.048 \times 10^{3}

Case 2 :Entropy of fusion of ice is \Delta S=1.2234 \times 10^{3}

Result : Entropy of vaporization of water is greater than entropy of fusion of ice

Explanation:

Entropy of closed system is given by \Delta S=\frac{\Delta Q}{T}

Where \Delta S is change of entropy, \Delta Q is change of heat and T is absolute temperature in kelvin

Case 1 : During vaporization of water

It is said that " 1.00 kg of water at 100 degree C is vaporized and converted to steam at 100 degree C"

Given Heat of vaporization of water is 2256 \times 10^{3} J/kg.

\Delta Q = mL

m=1 kg of water

L=2256 \times 10^{3} J/kg.

\Delta Q = mL = 2256 \times 10^{3}

Entropy of closed system is given by \Delta S=\frac{\Delta Q}{T}

Where, T=100+273=373K

\Delta S=\frac{ 2256 \times 10^{3}}{373}

\Delta S=6.048 \times 10^{3}

Thus, Entropy of vaporization of water is \Delta S=6.048 \times 10^{3}

Case 2 : During fusion of ice

It is said that " 1.00 kg of ice at 0 degree C is melted and converted to water at 0 degree C"

Given Heat of fusion of ice is 3.34 \times 10^{5} J/kg.

\Delta Q = mL

m=1 kg of ice

L=3.34 \times 10^{5}=334 \times 10^{3} J/kg.[tex]\Delta Q = mL = 334 \times 10^{3}

Entropy of closed system is given by \Delta S=\frac{\Delta Q}{T}

Where, T=0+273=273K

\Delta S=\frac{ 334 \times 10^{3}}{373}

\Delta S=1.2234\times 10^{3}

Thus, Entropy of fusion of ice is \Delta S=1.2234 \times 10^{3}

Therefore, Entropy of vaporization of water is greater than entropy of fusion of ice

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Two strings on a musical instrument are tuned to play at 196 hz (g) and 523 hz (c). (a) what are the first two overtones for eac
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(a) first two overtones for each string:
The first string has a fundamental frequency of 196 Hz. The n-th overtone corresponds to the (n+1)-th harmonic, which can be found by using
f_n = n f_1
where f1 is the fundamental frequency.

So, the first overtone (2nd harmonic) of the string is
f_2 = 2 f_1 = 2 \cdot 196 Hz = 392 Hz
while the second overtone (3rd harmonic) is
f_3 = 3 f_1 = 3 \cdot 196 Hz = 588 Hz

Similarly, for the second string with fundamental frequency f_1 = 523 Hz, the first overtone is
f_2 = 2 f_1 = 2 \cdot 523 Hz = 1046 Hz
and the second overtone is
f_3 = 3 f_1 = 3 \cdot 523 Hz = 1569 Hz

(b) The fundamental frequency of a string is given by
f=  \frac{1}{2L}  \sqrt{ \frac{T}{\mu} }
where L is the string length, T the tension, and \mu = m/L is the mass per unit of length. This part  of the problem says that the tension T and the length L of the string are the same, while the masses are different (let's calle them m_{196}, the mass of the string of frequency 196 Hz, and m_{523}, the mass of the string of frequency 523 Hz.
The ratio between the fundamental frequencies of the two strings is therefore:
\frac{523 Hz}{196 Hz} =  \frac{ \frac{1}{2L}  \sqrt{ \frac{T}{m_{523}/L} } }{\frac{1}{2L}  \sqrt{ \frac{T}{m_{196}/L} }}
and since L and T simplify in the equation, we can find the ratio between the two masses:
\frac{m_{196}}{m_{523}}=( \frac{523 Hz}{196 Hz} )^2 = 7.1

(c) Now the tension T and the mass per unit of length \mu is the same for the strings, while the lengths are different (let's call them L_{196} and L_{523}). Let's write again the ratio between the two fundamental frequencies
\frac{523 Hz}{196 Hz}= \frac{ \frac{1}{2L_{523}} \sqrt{ \frac{T}{\mu} } }{\frac{1}{2L_{196}} \sqrt{ \frac{T}{\mu} }} 
And since T and \mu simplify, we get the ratio between the two lengths:
\frac{L_{196}}{L_{523}}= \frac{523 Hz}{196 Hz}=2.67

(d) Now the masses m and the lenghts L are the same, while the tensions are different (let's call them T_{196} and T_{523}. Let's write again the ratio of the frequencies:
\frac{523 Hz}{196 Hz}= \frac{ \frac{1}{2L} \sqrt{ \frac{T_{523}}{m/L} } }{\frac{1}{2L} \sqrt{ \frac{T_{196}}{m/L} }}
Now m and L simplify, and we get the ratio between the two tensions:
\frac{T_{196}}{T_{523}}=( \frac{196 Hz}{523 Hz} )^2=0.14
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