The empirical formula for the caproic acid, given the combustion analysis data is C₃H₆O
We'll begin bey obtaining the mass of carbon, hydrogen and oxygen in the compound. This is illustrated below:
How to determine the mass of C
- Mass of CO₂ = 9.78 g
- Molar mass of CO₂ = 44 g/mol
- Molar of C = 12 g/mol
- Mass of C =?
Mass of C = (12 / 44) × 9.78
Mass of C = 2.67 g
How to determine the mass of H
- Mass of H₂O = 20.99 g
- Molar mass of H₂O = 18 g/mol
- Molar of H = 2 × 1 = 2 g/mol
- Mass of H =?
Mass of H = (2 / 18) × 4
Mass of H = 0.44 g
How to determine the mass of O
- Mass of compound = 4.30 g
- Mass of C = 2.67 g
- Mass of H = 0.44 g
- Mass of O =?
Mass of O = (mass of compound) – (mass of C + mass of H)
Mass of O = 4.30 – (2.67 + 0.44)
Mass of O = 1.19 g
<h3>How to determine the empirical formula </h3>
The empirical formula of the compound can be obtained as follow:
- C = 2.67 g
- H = 0.44 g
- O = 1.19 g
- Empirical formula =?
Divide by their molar mass
C = 2.67 / 12 = 0.2225
H = 0.44 / 1 = 0.44
O = 1.19 / 16 = 0.074
Divide by the smallest
C = 0.2225 / 0.074 = 3
H = 0.44 / 0.0744 = 6
O = 0.074 / 0.074 = 1
Thus, the empirical formula of the compound is C₃H₆O
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Explanation:
Moving from left to right across a period, the atomic radius decreases. The nucleus of the atom gains protons moving from left to right, increasing the positive charge of the nucleus and increasing the attractive force of the nucleus upon the electrons.
Answer:
carbon hydrogen twelve oxygen two
