<span>A chemist adds 155.0ml of a 4.10 X 10^-5 mmol/L of a zinc oxalate (ZnC2O4)solution to a reaction flask. Calculate the mass in micrograms of zinc oxalate the chemist has added to the flask.
1mmol = 10^-3 mol
Therefore 4.10*10^-5mmol = 4.10*10^-8mol
molar mass ZnC2O4 = 65.39+(2*12.011)+(4*15.99) = 153.372g/mol
You have 4.10*10^-8 mol/litre =153.372 * 4.10*10^-8 = 6.29*10^-6 grams / litre (* see below)
But you have 155ml. Mass of ZnC2O4 = 155/1000*6.29*10^-6 g
Mass is = 9.75*10^-7 grams
1µg = 10^-6 g
You then have 9.75*10^-7/10^-6 = 0.975µg ZnC2O4
(*see below) at this point you could have said:
1µg = 10^-6 g therefore you have a solution of 6.29µg per litre,
155ml = 6.29*155/1000 = 0.975µg ZnC2O4</span>
Explanation:
Let us assume that total mass of the solution is 100 g. And, as it is given that acetic acid solution is 12% by mass which means that mass of acetic acid is 12 g and 88 g is the water.
Now, calculate the number of moles of acetic acid as its molar mass is 60 g/mol.
No. of moles = 
= 
= 0.2 mol
Molarity of acetic acid is calculated as follows.
Density = 
1 g/ml = 
volume = 100 ml
Hence, molarity = 
= 
= 2 mol/l
As reaction equation for the given reaction is as follows.
So, moles of NaOH = moles of acetic acid
Let us suppose that moles of NaOH are "x".
(as 1 L = 1000 ml)
x = 20 L
Thus, we can conclude that volume of NaOH required is 20 ml.
5.6L of O2 means we have 0.25 moles of O2.
As, 1 mole has 6.023*10^23 molecules,
0.25 moles of O2 will have 0.25*6.023*10^23 molecules=1.50575*10^23 molecules
and as 1 molecule of O2 has 2 atoms, so, 1.50575*10^23 molecules will have 2*1.50575*10^23 atoms=3.0115*10^23 atoms of O.
Answer:
Explanation:
<u>1) First law of thermodynamic (energy balance)</u>
- Heat released by the the hot water (345K ) = Heat absorbedby the cold water (298 K) + Heat absorbed by the calorimeter
<u>2) Energy change of each substance:</u>
Heat released or absorbed = mass × Specific heat × change in temperature
- density of water: you may take 0.997 g/ ml as an average density for the water.
- mass of water: mass = density × volume = 50.0 ml × 0.997 g/ml = 49.9 g
- Specif heat of water: 1 cal / g°C
- Heat released by the hot water:
Heat₁ = 49.9 g × 1 cal / g°C × (345 K - 317 K) = 49.9 g × 1 cal / g°C × (28K)
- Heat absorbed by the cold water:
Heat₂ = 49.9 g × 1 cal / g°C × (317 K - 298 K) = 49.9 g × 1 cal / g°C × (19K)
- Heat absorbed by the calorimeter
Heat₃ = Ccal × (317 K - 298 K) = Ccal × (19K)
<u>4) Balance</u>
49.9 g × 1 cal / g°C × (28 K) = 49.9 g × 1 cal / g°C × (19 K) + Ccal × (19 K)
Ccal = [49.9 g × 1 cal / g°C × (28 K) - 49.9 g × 1 cal / g°C × (19 K) ] / 19K
Ccal = 23.6 cal/ K
- Convert to cal / K to Joule / K
23.6 cal / K × 4.18 J / cal = 98.6 J/K
Which rounded to 2 signficant figures leads to 99 J/k, which is the first choice.
