The answer is (4) Ag(s)
Solid Silver has a Face Centered Cubic crystal structure.
The remaining choices are gases (H2 & Ar) and liquid (Br). Liquids and gases do not form crystal structures as their atoms are loose.
The answer is B. Continental Drift (Confidently)
Scratching causes cracks and crevices on the surface of the flask (though microscopically). These will act as favorable sites for nucleation, which leads to the formation of crystals.
I believe the answer is A