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Viefleur [7K]
3 years ago
15

Draw the structure of the bromohydrin formed when (Z)-3-hexene reacts with Br2/H2O. Use the wedge/hash bond tools to indicate st

ereochemistry where it exists. If the reaction produces a racemic mixture, draw both stereoisomers. Separate multiple products using the sign from the drop-down menu.

Chemistry
1 answer:
Ipatiy [6.2K]3 years ago
5 0

Answer:

(3R,4R)-4-bromohexan-3-ol

Explanation:

In this case, we have  reaction called <u>halohydrin formation</u>. This is a <u>markovnikov reaction</u> with <u>anti configuration</u>. Therefore the halogen in this case "Br" and the "OH" must have <u>different configurations</u>. Additionally, in this molecule both carbons have the <u>same substitution</u>, so the "OH" can go in any carbon.

Finally, in the product we will have <u>chiral carbons</u>, so we have to find the absolute configuration for each carbon. On carbon 3 we will have an "R" configuration on carbon 4 we will have also an "R" configuration. (See figure 1)

I hope it helps!

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Mghso4.5h2O name and molar mass
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8 0
3 years ago
The size of camphor kept in store house gradually decrease in size after few а days? ​
zzz [600]

Answer:

Because it goes through the process of sublimation.

Explanation:

4 0
2 years ago
what is the pH of a solution prepared from solid, neutral 2-nitrophenol providing a fromal concentration of 0.0353M, given that
REY [17]

Answer:

pH = 4.34

Explanation:

pH= -1/2(logKa) -1/2(log C)

= -1/2( log 5.98*10^-8) -1/2(log 0.0353)

=-1/2(-7.22)-1/2(-1.45)

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7 0
3 years ago
A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalenc
Lorico [155]

Answer:

a. 0.180M of C₆H₅NH₂

b. 0.0887M C₆H₅NH₃⁺

c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

Moles required to reach equivalence point are:

Moles HCl = 0.02567L ₓ (0.175mol / L) = 4.492x10⁻³ moles HCl = moles C₆H₅NH₂

As the original solution had a volume of 25.0mL = 0.0250L:

4.492x10⁻³ moles C₆H₅NH₂ / 0.0250L = 0.180M of C₆H₅NH₂

b. At equivalence point, moles of C₆H₅NH₃⁺ are equal to initial moles of C₆H₅NH₂, that is 4.492x10⁻³ moles

But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

<em>2.5x10⁻⁵ = [C₆H₅NH₂] [H₃O⁺] / [C₆H₅NH₃⁺]</em>

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

Solving for X:

X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

<h3>pH = 2.83</h3>

7 0
2 years ago
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Answer:

Determine how many formula units are in 2.35 moles of lithium phosphite?

Explanation:

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3 years ago
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