the temperature is decreased
Answer:
136.63 °C
Explanation:
ΔTb=Tb solution - Tb pure
Where; Tb pure = 133.60°C
molar mass of solute = 121.14 g/mol
number of moles of solute; 52.2g/121.14 g/mol = 0.431 moles
molality = 0.431 moles/350 * 10^-3 = 1.23 molal
Then;
ΔTb = Kb * m * i
Kb = 2.46°C kg mol^-1
m = 1.23 molal
i = 1
ΔTb = 2.46 * 1.23 * 1
ΔTb = 3.03 °C
Hence;
Tb solution = ΔTb + Tb pure
Tb solution = 3.03 °C + 133.60°C
Tb solution = 136.63 °C
Answer:
The Sandmeyer reaction is a chemical reaction used to synthesize aryl halides from aryl diazonium salts using copper salts as reagents or catalysts. It is an example of a radical-nucleophilic aromatic substitution.
Answer:
2.79 °C/m
Explanation:
When a nonvolatile solute is dissolved in a pure solvent, the boiling point of the solvent increases. This property is called ebullioscopy. The temperature change (ΔT) can be calculated by:
ΔT = Kb*W*i
Where Kb is the ebullioscopy constant for the solvent, W is the molality and i is the van't Hoff factor.
W = m1/(M1*m2)
Where m1 is the mass of the solute (in g), M1 is the molar mass of the solute, and m2 is the mass of the solvent (in kg).
The van't Hoff factor represents the dissociation of the elements. For an organic molecule, we can approximate i = 1. Thus:
m1 = 2.00 g
M1 = 147 g/mol
m2 = 0.0225 kg
W = 2/(147*0.0225)
W = 0.6047 mol/kg
(82.39 - 80.70) = Kb*0.6047*1
0.6047Kb = 1.69
Kb = 2.79 °C/m
Answer:
a. -29.8 kJ/mol-rxn
Explanation:
For a chemical reaction system the forward and reverse rate are equal. The standard molar enthalpy formation of NH3 is -45.9 kJ/mol. For the enthalpy of NH3 (8) the molar enthalpy is -29.8kJ/mol. The molar mass of N2 = 28.02g/mol. Molar enthalpy of formation is standard amount of substance produced in the formation of a reaction. The molar enthalpy is the change in enthalpy due to reaction per mole.
