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Radioactive decay => C = Co { e ^ (- kt) |
Data:
Co = 2.00 mg
C = 0.25 mg
t = 4 hr 39 min
Time conversion: 4 hr 39 min = 4.65 hr
1) Replace the data in the equation to find k
C = Co { e ^ (-kt) } => C / Co = e ^ (-kt) => -kt = ln { C / Co} => kt = ln {Co / C}
=> k = ln {Co / C} / t = ln {2.00mg / 0.25mg} / 4.65 hr = 0.44719
2) Use C / Co = 1/2 to find the hallf-life
C / Co = e ^ (-kt) => -kt = ln (C / Co)
=> -kt = ln (1/2) => kt = ln(2) => t = ln (2) / k
t = ln(2) / 0.44719 = 1.55 hr.
Answer: 1.55 hr
A solution (in this experiment solution of NaNO₃) freezes at a lower temperature than does the pure solvent (deionized water). The higher the
solute concentration (sodium nitrate), freezing point depression of the solution will be greater.
Equation describing the change in freezing point:
ΔT = Kf · b · i.
ΔT - temperature change from pure solvent to solution.
Kf - the molal freezing point depression constant.
b - molality (moles of solute per kilogram of solvent).
i - Van’t Hoff Factor.
First measure freezing point of pure solvent (deionized water). Than make solutions of NaNO₃ with different molality and measure separately their freezing points. Use equation to calculate Kf.
Answer:
1. pH = 1.23.
2. 
Explanation:
Hello!
1. In this case, for the ionization of H2C2O4, we can write:
It means, that if it is forming a buffer solution with its conjugate base in the form of KHC2O4, we can compute the pH based on the Henderson-Hasselbach equation:
![pH=pKa+log(\frac{[base]}{[acid]} )](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%28%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D%20%29)
Whereas the pKa is:
The concentration of the base is 0.347 M and the concentration of the acid is 0.347 M as well, as seen on the statement; thus, the pH is:
2. Now, since the addition of KOH directly consumes 0.070 moles of acid, we can compute the remaining moles as follows:
It means that the acid remains in excess yet more base is yielded due to the effect of the OH ions provided by the KOH; therefore, the undergone chemical reaction is:
Which is also shown in net ionic notation.
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