The flavor and odor of fruits comes primarily from the esters they contain. For example, a major component in the flavor of oran
ges is octyl acetate. Draw the organic products formed when octyl acetate reacts with aqueous sodium hydroxide.
1 answer:
Answer:
Explanation:
Concepts and reason
This problem is based on the concept of hydrolysis of esters.
An ester is hydrolyzed to a carboxylic acid and an alcohol when treated with aqueous acid or aqueous base. Under alkaline conditions, the carboxylic acid is obtained in the form as its salt.
Fundamentals
Alkaline hydrolysis of ester is done with strong base {\\rm{NaOH}}NaOHand {\\rm{O}}{{\\rm{H}}^ - }OH\u2212acts as nucleophilic reagent. This reaction is reversible, since carboxylate anion has tendency to react with an alcohol and gives back ester.
Step-by-step
Step 1 of 2
Attack of [{ m{O}}{{ m{H}}^ - }]on carbonyl take place as follows resulting formation of tetrahedral intermediate:
\u043e\u043d\u043e\u043d
Explanation | Hint for next step
The {\\rm{O}}{{\\rm{H}}^ - }OH\u2212nucleophile attacks on the electrophilic carbon of an ester {\\rm{C}} = {\\rm{O}}C=O and forms tetrahedral intermediate after breaking the \\pi\u03c0-bond.
Step 2 of 2
Hydrolysis of product formed from step 1 followed by reaction with {\\rm{NaOH}}NaOHis as follows:
The products of the reaction are:
Explanation | Common mistakes
On the reaction of octyl acetate with aqueous sodium hydroxide, the products octyl alcohol and acetate ion are formed after omitting the {\\rm{N}}{{\\rm{a}}^ + }Na+ions.
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Answer: The reaction order with respect to A is m
Explanation:
Order of the reaction is defined as the sum of the concentration of terms on which the rate of the reaction actually depends. It is the sum of the exponents of the molar concentration in the rate law expression.
Elementary reactions are defined as the reactions for which the order of the reaction is same as its molecularity and order with respect to each reactant is equal to its stoichiometric coefficient as represented in the balanced chemical reaction.
For the given reaction:
In this equation, the order with respect to each reactant is not equal to its stoichiometric coefficient which is represented in the balanced chemical reaction.
Hence, this is not considered as an elementary reaction.
Order with respect to A = m
Order with respect to B = n
Overall order = m+n
Thus order with respect to A is m.
Answer : 0.8663 Kg of chalcopyrite must be mined to obtained 300 g of pure Cu.
Solution : Given,
Mass of Cu = 300 g
Molar mass of Cu = 63.546 g/mole
Molar mass of = 183.511 g/mole
- First we have to calculate the moles of Cu.
The moles of Cu = 4.7209 moles
From the given chemical formula, we conclude that the each mole of compound contain one mole of Cu.
So, The moles of Cu = Moles of = 4.4209 moles
- Now we have to calculate the mass of
.
Mass of = Moles of
× Molar mass of
= 4.4209 moles × 183.511 g/mole = 866.337 g
Mass of = 866.337 g = 0.8663 Kg (1 Kg = 1000 g)
Therefore, 0.8663 Kg of chalcopyrite must be mined to obtained 300 g of pure Cu.