The electronegativity of nitrogen (N) is 3.0, while the electronegativity of hydrogen (H) is 2.1. As it can be seen that nitrogen (N) is more electronegative than that of hydrogen (H),
So electron pairs are attracted towards nitrogen and thus it carries a partial negative charge and hydrogen carries a partial positive charge. The image of electron distribution is attached as follows.
Thus NH₃ is a polar molecule .
Answer : 0.0392 grams of Zn metal would be required to completely reduced the vanadium.
Explanation :
Let us rewrite the given equations again.



On adding above equations, we get the following combined equation.

We have 12.1 mL of 0.033 M solution of VO₂⁺.
Let us find the moles of VO₂⁺ from this information.

From the combined equation, we can see that the mole ratio of VO₂⁺ to Zn is 2:3.
Let us use this as a conversion factor to find the moles of Zn.

Let us convert the moles of Zn to grams of Zn using molar mass of Zn.
Molar mass of Zn is 65.38 g/mol.

We need 0.0392 grams of Zn metal to completely reduce vanadium.
126 grams of H2O is formed.
Explanation:
Data given:
volume of the gas = 88 Liters
pressure = 720 mm Hg or 0.947 atm
temperature T = 22 Degrees or 295.15 K
R = 0.08021 atm L/mole K
n =?
The formula is used is of ideal gas law to know the number of moles of CH4 undergoing combustion.
PV = nRT
n = 
putting the values in the equation
= 0.947 X 88/ 0.08021 X 295.15
n = 3.5 moles
balanced reaction for combustion of methane
CH4 + O2 ⇒ CO2 + 2H20
1 mole of CH4 undergoes combustion to form 2 moles of water
3.5 moles will give x moles of water
2/1 = x/3.5
x = 7 moles of water (atomic mass of water = 18 gram/mole)
mass = atomic mass x number of moles
mass = 18 x 7
=126 grams of water is formed.