Answer:
q = -6464.9 kJ
Explanation:
We are given that the heat of combustion is ∆H° = −394 kJ per mol of carbon.Therefore what we need to do is calculate how many moles of C are in the lump of coal by finding its mass since the density is given.
vol = 5.6 cm x 5.1 cm x 4.6 cm = 131.38 cm³
m = d x v = 1.5 g/cm³ x 131.38 cm³ = 197.06 g
mol C = m/MW = 197.06 g/ 12.01g/mol = 16.41 mol
q = −394 kJ /mol C x 16.41 mol C = -6464.9 kJ
Positron emission = emission of a positron and a neutrino when a
proton is convert into a neutron. The total number of particles in the
nucleus doesn't change, -1 proton +1 neutron
It's a spontaneous reaction for some nucleus.
eg:
Positron = e+
Neutrino=ve
O-15 --> N-15 + e+ +ve
Electron
capture= A nucleus absorb an electron while a proton is convert in a
neutron and emit a neutrino. The total number of particles in the
nucleus doesn't change, -1 proton +1 neutron
eg:
Al-26 +e- --> Mg-26 + ve
Electron
capture and positron emission are two mechanisms to explain the decay
of some unstable isotopes. Electron capture is usually observed when the
energy difference between the initial and final state is low. Mainly
because of the larger amount of kinetic energy need for the expulsion
two particles with the positron emission mechanism.
Answer:
Step 1) hydrolysis using NaOH/H2O to form benzylalcohol
Step2) oxidation to Carboxylic acid using KMnO4 followed by decarboxylation to form benzene
3) friedel craft acylation using CH3COCl/AlCl3
Explanation:
The above 3 steps will yield acetophenone from methylbenzoate
Answer:
Ethane would have a higher boiling point.
Explanation:
In this case, for the lewis structures, we have to keep in mind that all atoms must have <u>8 electrons</u> (except hydrogen). Additionally, each carbon would have <u>4 valence electrons</u>, with this in mind, for methane we have to put the hydrogens around the carbon, and with this structure, we will have 8 electrons for the carbon. In ethane, we will have a bond between the carbons, therefore we have to put three hydrogens around each carbon to obtain 8 electrons for each carbon.
Now, the main difference between methane and ethane is an <u>additional carbon</u>. In ethane, we have an additional carbon, therefore due to this additional carbon, we will have <u>more area of interaction</u> for ethane. If we have more area of interaction we have to give <u>more energy</u> to the molecule to convert from liquid to gas, so, the ethane will have a higher boiling point.
I hope it helps!
