Answer:
They can fix carbon at the lower CO2 concentrations that develop when the stomata are closed.
Explanation:
In order to conserve the substrate Ribulose biphosphate(RuBP) which must react with CO2,, and to avoid wasteful photorespiration reaction of RuBP with oxygen. which are both catalysed by enzyme Rubisco; C4 plants formed a 4C-compounds -oxaloacatate . While keeping RuBP and enzyme Rubisco in the bundle sheath away from oxygen.
The C02 is rather absorbed by mesopyll cell in contact with air and combines with 3C-Phosphoenopyruvate, a reaction catalysed by Phosphoenocarboxylase, to form 4C-oxaloacetate.
The latter is converted to 4C -Malate, which is shunted from the mesophyll into the bundle shealth where Rubisco and RuBP are concentrated.
Therefore when the stomata is closed,C4 plants can fixed Carbon as Oxaloacetate and Malate, in the bundle sheath,despite the closed Stomata, because of the anatomy which separated the externally contact mesophyll cells from the airtight bundle sheath cells.