The question is incomplete, here is the complete question:
The rate of certain reaction is given by the following rate law:
![rate=k[H_2]^2[NH_3]](https://tex.z-dn.net/?f=rate%3Dk%5BH_2%5D%5E2%5BNH_3%5D)
At a certain concentration of ![H_2 and [tex]I_2, the initial rate of reaction is 0.120 M/s. What would the initial rate of the reaction be if the concentration of [tex]H_2 were halved.Answer : The initial rate of the reaction will be, 0.03 M/sExplanation :Rate law expression for the reaction:[tex]rate=k[H_2]^2[NH_3]](https://tex.z-dn.net/?f=H_2%20and%20%5Btex%5DI_2%2C%20the%20initial%20rate%20of%20reaction%20is%200.120%20M%2Fs.%20What%20would%20the%20initial%20rate%20of%20the%20reaction%20be%20if%20the%20concentration%20of%20%5Btex%5DH_2%20were%20halved.%3C%2Fp%3E%3Cp%3E%3Cstrong%3EAnswer%20%3A%20The%20initial%20rate%20of%20the%20reaction%20will%20be%2C%200.03%20M%2Fs%3C%2Fstrong%3E%3C%2Fp%3E%3Cp%3E%3Cstrong%3EExplanation%20%3A%3C%2Fstrong%3E%3C%2Fp%3E%3Cp%3E%3Cstrong%3ERate%20law%20expression%20for%20the%20reaction%3A%3C%2Fstrong%3E%3C%2Fp%3E%3Cp%3E%5Btex%5Drate%3Dk%5BH_2%5D%5E2%5BNH_3%5D)
As we are given that:
Initial rate = 0.120 M/s
Expression for rate law for first observation:
....(1)
Expression for rate law for second observation:
....(2)
Dividing 2 by 1, we get:
![\frac{R}{0.120}=\frac{k(\frac{[H_2]}{2})^2[NH_3]}{k[H_2]^2[NH_3]}](https://tex.z-dn.net/?f=%5Cfrac%7BR%7D%7B0.120%7D%3D%5Cfrac%7Bk%28%5Cfrac%7B%5BH_2%5D%7D%7B2%7D%29%5E2%5BNH_3%5D%7D%7Bk%5BH_2%5D%5E2%5BNH_3%5D%7D)


Therefore, the initial rate of the reaction will be, 0.03 M/s
Radioactive decay => C = Co { e ^ (- kt) |
Data:
Co = 2.00 mg
C = 0.25 mg
t = 4 hr 39 min
Time conversion: 4 hr 39 min = 4.65 hr
1) Replace the data in the equation to find k
C = Co { e ^ (-kt) } => C / Co = e ^ (-kt) => -kt = ln { C / Co} => kt = ln {Co / C}
=> k = ln {Co / C} / t = ln {2.00mg / 0.25mg} / 4.65 hr = 0.44719
2) Use C / Co = 1/2 to find the hallf-life
C / Co = e ^ (-kt) => -kt = ln (C / Co)
=> -kt = ln (1/2) => kt = ln(2) => t = ln (2) / k
t = ln(2) / 0.44719 = 1.55 hr.
Answer: 1.55 hr
The person above is trying to give you a virus
The Reaction is spontaneous when temperature is 430 K. Hence, Option (C) is correct.
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What is Spontaneous reaction ?</h3>
Reactions are favorable when they result in a decrease in enthalpy and an increase in entropy of the system.
When both of these conditions are met, the reaction occurs naturally.
Spontaneous reaction is a reaction that favors the formation of products at the conditions under which the reaction is occurring.
According to Gibb's equation:
ΔG = ΔH - TΔS
ΔG = Gibbs free energy
ΔH = enthalpy change = +62.4 kJ/mol
ΔS = entropy change = +0.145 kJ/molK
T = temperature in Kelvin
- ΔG = +ve, reaction is non spontaneous
- ΔG = -ve, reaction is spontaneous
- ΔG = 0, reaction is in equilibrium
ΔH - TΔS = 0 for reaction to be spontaneous
T = ΔH / ΔS
Here,
T = 500K
Thus the Reaction is spontaneous when temperature is 500 K.
Learn more about Gibbs free energy here ;
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