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Kamila [148]
3 years ago
9

If 20 ml of gas is subjected to a tempature change from 10 Celsius to 100 Celsius and a pressure change from 1 atm to 10 atm, th

e expression best representing the new volume is?
Chemistry
1 answer:
serg [7]3 years ago
4 0

Answer:

V₂ = 2.64 mL

Explanation:

Given data:

Initial volume = 20 mL

Initial pressure = 1 atm

Initial temperature = 10°C (10 +273 = 283 K)

Final temperature = 100°C (100+273 = 373 K)

Final volume = ?

Final pressure = 10 atm

Formula:  

P₁V₁/T₁ = P₂V₂/T₂  

P₁ = Initial pressure

V₁ = Initial volume

T₁ = Initial temperature

P₂ = Final pressure

V₂ = Final volume

T₂ = Final temperature

Solution:

V₂ = P₁V₁ T₂/ T₁ P₂  

V₂ = 1 atm. 20 mL . 373 K / 283 K. 10 atm

V₂ = 7460 mL.K.atm / 2830 K.atm

V₂ = 2.64 mL

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The question is incomplete, here is the complete question:

The rate of certain reaction is given by the following rate law:

rate=k[H_2]^2[NH_3]

At a certain concentration of H_2 and [tex]I_2, the initial rate of reaction is 0.120 M/s. What would the initial rate of the reaction be if the concentration of [tex]H_2 were halved.Answer : The initial rate of the reaction will be, 0.03 M/sExplanation :Rate law expression for the reaction:[tex]rate=k[H_2]^2[NH_3]

As we are given that:

Initial rate = 0.120 M/s

Expression for rate law for first observation:

0.120=k[H_2]^2[NH_3] ....(1)

Expression for rate law for second observation:

R=k(\frac{[H_2]}{2})^2[NH_3] ....(2)

Dividing 2 by 1, we get:

\frac{R}{0.120}=\frac{k(\frac{[H_2]}{2})^2[NH_3]}{k[H_2]^2[NH_3]}

\frac{R}{0.120}=\frac{1}{4}

R=0.03M/s

Therefore, the initial rate of the reaction will be, 0.03 M/s

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3 years ago
Lt takes 4 hr 39 min for a 2.00-mg sample of radium-230 to decay to 0.25 mg. what is the half-life of radium-230?
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Radioactive decay => C = Co { e ^ (- kt) |

Data:

Co = 2.00 mg
C = 0.25 mg
t = 4 hr 39 min

Time conversion: 4 hr 39 min = 4.65 hr

1) Replace the data in the equation to find k

C = Co { e ^ (-kt) } => C / Co = e ^ (-kt) => -kt = ln { C / Co} => kt = ln {Co / C}

=> k = ln {Co / C} / t =  ln {2.00mg / 0.25mg} / 4.65 hr = 0.44719

2) Use C / Co  = 1/2 to find the hallf-life

C / Co = e ^ (-kt) => -kt = ln (C / Co)

=> -kt = ln (1/2) => kt = ln(2) => t = ln (2) / k

t = ln(2) / 0.44719 = 1.55 hr.

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The Reaction is spontaneous when temperature is 430 K. Hence, Option (C) is correct.

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Reactions are favorable when they result in a decrease in enthalpy and an increase in entropy of the system.

When both of these conditions are met, the reaction occurs naturally.

Spontaneous reaction is a reaction that favors the formation of products at the conditions under which the reaction is occurring.

According to Gibb's equation:

ΔG = ΔH - TΔS

ΔG = Gibbs free energy

ΔH = enthalpy change  = +62.4 kJ/mol

ΔS = entropy change  = +0.145 kJ/molK

T = temperature in Kelvin

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  • ΔG = -ve, reaction is spontaneous
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ΔH - TΔS = 0 for reaction to be spontaneous

T = ΔH / ΔS

Here,

T = 500K

Thus the Reaction is spontaneous when temperature is 500 K.

Learn more about Gibbs free energy here ;

https://brainly.in/question/13372282

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