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enyata [817]
3 years ago
7

A sample of oxalic acid (a diprotic acid of the formula H2C2O4) is dissolved in enough water to make 1.00 L of solution. A 100.0

mL sample of this solution is titrated with a solution of sodium hydroxide of concentration 0.750 M and requires 20.0 mL of sodium hydroxide to reach the end point. Calculate the mass of the original oxalic acid sample.
Chemistry
1 answer:
OleMash [197]3 years ago
7 0

<u>Answer:</u> The mass of original oxalic acid sample is 6.75 grams

<u>Explanation:</u>

To calculate the concentration of acid, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is H_2C_2O_4

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=2\\M_1=?M\\V_1=100.0mL\\n_2=1\\M_2=0.750M\\V_2=20.0mL

Putting values in above equation, we get:

2\times M_1\times 100.0=1\times 0.750\times 20.0\\\\M_1=\frac{1\times 0.750\times 20.0}{2\times 100.0}=0.075M

To calculate the mass of solute, we use the equation used to calculate the molarity of solution:

\text{Molarity of the solution}=\frac{\text{Mass of solute}}{\text{Molar mass of solute}\times \text{Volume of solution (in L)}}

Given mass of oxalic acid = ? g

Molar mass of oxalic acid = 90 g/mol

Molarity of solution = 0.075 M

Volume of solution = 1.00 L

Putting values in above equation, we get:

0.075M=\frac{\text{Mass of oxalic acid}}{90g/mol\times 1L}\\\\\text{Mass of oxalic acid}=(0.075\times 90\times 1)=6.75g

Hence, the mass of original oxalic acid sample is 6.75 grams

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