An element is a pure substance
You can use Le Chatelier's Principle to describe the equilibrium shift.
Le Chaterlier's Principle states that: "<span>If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change."
Thus, if you heat up the reaction, the equilibrium shift favors the endothermic reaction. If you increase pressure (if gases are involved), the shift favors the reaction that produces less gaseous products (to counteract pressure) and so on.</span>
<u>Answer:</u>
<u>For a:</u> The wavelength of light is 
<u>For b:</u> The light is getting absorbed
<u>Explanation:</u>
To calculate the wavelength of light, we use Rydberg's Equation:

Where,
= Wavelength of radiation
= Rydberg's Constant = 
= Higher energy level = 7
= Lower energy level = 3
Putting the values in above equation, we get:

Hence, the wavelength of light is 
There are two ways in which electrons can transition between energy levels:
- <u>Absorption spectra:</u> This type of spectra is seen when an electron jumps from lower energy level to higher energy level. In this process, energy is absorbed.
- <u>Emission spectra:</u> This type of spectra is seen when an electron jumps from higher energy level to lower energy level. In this process, energy is released in the form of photons.
As, the electron jumps from lower energy level to higher energy level. The wavelength is getting absorbed.
<u>Given:</u>
Mass of solvent water = 4.50 kg
Freezing point of the solution = -11 C
Freezing point depression constant = 1.86 C/m
<u>To determine:</u>
Moles of methanol to be added
<u>Explanation:</u>
The freezing point depression ΔTf is related to the molality m through the constant kf, as follows:
ΔTf = kf*m
where ΔTf = Freezing point of pure solvent (water) - Freezing pt of solution
ΔTf = 0 C - (-11.0 C) = 11.0 C
m = molality = moles of methanol/kg of water = moles of methanol/4.50 kg
11.0 = 1.86 * moles of methanol/4.50
moles of methanol = 26.613 moles
Ans: Thus around 26.6 moles of methanol should be added to 4.50 kg of water.