It can be found that 337.5 g of AgCl formed from 100 g of silver nitrate and 258.4 g of AgCl from 100 g of CaCl₂.
<u>Explanation:</u>
2AgNO₃ + CaCl₂ → 2 AgCl + Ca(NO₃)₂
We have to find the amount of AgCl formed from 100 g of Silver nitrate by writing the expression.

= 337.5 g AgCl
In the same way, we can find the amount of silver chloride produced from 100 g of Calcium chloride.
It can be found as 258.4 g of AgCl produced from 100 g of Calcium chloride.
Explanation:
The given cell reaction is as follows.

Hence, reactions taking place at the cathode and anode are as follows.
At anode ; Oxidation-half reaction :
...... (1)
At cathode; Reduction-half reaction :
....... (2)
Hence, balance the half reactions by multiplying equation (1) by 2 and equation (2) by 3.
Therefore, net cell reaction is as follows.

Net reaction: 
Thus, we can conclude that the overall cell reaction is as follows.

What exactly is the question you are asking?
POH will be -log[conc of OH]
-log (3.9E-08) = 7.409
pH = 14- pOH
pH = 14 - 7.409
pH = 6.59