<span>
Mn²⁺ + 4H2O -----> MnO4⁻ + 8H⁺ +5e⁻ /*2
<span>NaBiO3 +6H⁺ +2e⁻ -----> Bi³⁺ + Na⁺ + 3H2O /*5
</span>2Mn²⁺ + 5 NaBiO3+8H2O+30H⁺ ---> 2MnO4⁻ +5Bi³⁺ + 5Na⁺ +16H⁺ +15H2O
</span>2Mn²⁺ + 5 NaBiO3+14H⁺ ---> 2MnO4⁻ +5Bi³⁺ + 5Na⁺ +7H2O
There are 7 water molecules in this reaction.

1 mole of nitric acid produce 1 mole of ammonium nitrate.
moles in 5000 kg of ammonium nitrate :
( molecular mass of ammonium nitrate is 80 gm/mol )
So, number of moles of nitric acid required are also 62500 moles.
Mass of 62500 moles of nitric acid :

Hence, this is the required solution.
Answer:therefore the oxidation state of sulphur is +6 in the compound CaSO4.
Explanation:
Explanation:
Since, it is shown that the reaction has been reversed. Therefore, value of
will become
.
Hence, new 
= 
= 20
Also, the number of moles of each reactant has been halved. So,
for the reaction
will also get halved.
Therefore,
=
= 
= 4.47
As the value of
is given as +39.0 kJ. So, it means that the reaction is endothermic in nature. So, energy of reactants will be more than the products. Hence, according to Le Chatelier's principle reaction will move in the forward direction.
As a result,
will also increase with increase in temperature.