Answer:
9.36
Explanation:
Sodium formate is the conjugate base of formic acid.
Also,
for sodium formate is 
Given that:
of formic acid = 
And, 
So,
Concentration = 0.35 M
HCOONa ⇒ Na⁺ + HCOO⁻
Consider the ICE take for the formate ion as:
HCOO⁻ + H₂O ⇄ HCOOH + OH⁻
At t=0 0.35 - -
At t =equilibrium (0.35-x) x x
The expression for dissociation constant of sodium formate is:
![K_{b}=\frac {[OH^-][HCOOH]}{[HCOO^-]}](https://tex.z-dn.net/?f=K_%7Bb%7D%3D%5Cfrac%20%7B%5BOH%5E-%5D%5BHCOOH%5D%7D%7B%5BHCOO%5E-%5D%7D)
Solving for x, we get:
x = 0.44×10⁻⁵ M
pOH = -log[OH⁻] = -log(0.44×10⁻⁵) = 4.64
pH + pOH = 14
So,
<u>pH = 14 - 4.64 = 9.36</u>
Answer:
ΔH = -470.4kJ
Explanation:
It is possible to sum 2 or more reactions to obtain the ΔH of the reaction you want to study (Hess's law). Using the reactions:
1. CaC2(s) + 2H2O(l) → C2H2(g) + Ca(OH)2(s)ΔH = −414kJ
2. 6C2H2(g) + 3CO2(g) + 4H2O(g) → 5CH2CHCO2H(g)ΔH = 132kJ
6 times the reaction 1.
6CaC2(s) + 12H2O(l) → 6C2H2(g) + 6Ca(OH)2(s)ΔH = −414kJ*6 = -2484kJ
This reaction + 2:
6CaC2(s) + 3CO2(g) + 16H2O(l) → + 6Ca(OH)2(s) + 5CH2CHCO2H(g) ΔH = -2484kJ + 132kJ = -2352kJ
As we want to calculate the net change enthalpy in the formation of just 1 mole of acrylic acid we need to divide this last reaction in 5:
6/5CaC2(s) + 3/5CO2(g) + 16/5H2O(l) → + 6/5Ca(OH)2(s) + CH2CHCO2H(g) ΔH = -2352kJ / 5
<h3>ΔH = -470.4kJ</h3>
Answer:
1. V2.
2. 299K.
3. 451K
4. 0.25 x 451 = V2 x 299
Explanation:
1. The data obtained from the question include:
Initial volume (V1) = 0.25mL
Initial temperature (T1) = 26°C
Final temperature (T2) = 178°C
Final volume (V2) =.?
2. Conversion from celsius to Kelvin temperature.
T(K) = T (°C) + 273
Initial temperature (T1) = 26°C
Initial temperature (T1) = 26°C + 273 = 299K
3. Conversion from celsius to Kelvin temperature.
T(K) = T (°C) + 273
Final temperature (T2) = 178°C
Final temperature (T1) = 178°C + 273 = 451K
4. Initial volume (V1) = 0.25mL
Initial temperature (T1) = 299K
Final temperature (T2) = 451K
Final volume (V2) =.?
V1 x T2 = V2 x T1
0.25 x 451 = V2 x 299
