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saw5 [17]
3 years ago
7

The specific rotation of (S)-2-butanol is +13.5. If 0.119 g of its enantiomer is dissolved in 10.0 mL of ethanol and

Chemistry
1 answer:
larisa86 [58]3 years ago
7 0

Answer:

+15.8°

Explanation:

The formula for the observed rotation (α) of an optically active sample is

α = [α]<em>lc </em>

where

<em>l</em> = the cell path length in decimetres

<em>c</em> = the concentration in units of g/100 mL

[α] = the specific rotation in degrees  

1. Convert the concentration to units of g/100 mL

c = \frac{\text{0.119 g}}{\text{10.0 mL}} \times \frac{10 }{10 } =\frac{\text{1.19 g}}{\text{100 mL}}

2. Calculate the observed rotation

\alpha = (+13.3 ^{\circ}) \times 1.19 \times 1 = +15.8^{\circ}

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garik1379 [7]

Balanced chemical equation is 3CH₃CH₂OH + 2Cr₂O₇²⁻ + 16H⁺ → 3CH₃COOH + 4Cr³⁺ + 11H₂O.

<h3>What is Balanced Chemical Equation ?</h3>

The balanced chemical equation is the equation in which the number of atoms on the reactant side is equal to the number of atoms on the product side in an equation.

The chemical equation

CH₃CH₂OH + Cr₂O₇²⁻ → CH₃COOH + Cr³⁺

First assign the oxidation number for each atom in the equation.

\overset{+3}{C}\overset{+1}{H_3} \overset{-1}{C} \overset{+1}{H_2} \overset{-2}{O} \overset{+1}{H} + \overset{+6}{Cr_2} \overset{-2}{O_7} + \overset{+1}{H} \rightarrow \overset{+3}{C}\overset{+1}{H_3} \overset{+3}{C}\overset{-2}{O} \overset{-2}{O} \overset{+1}{H} + \overset{+3}{Cr}

Oxidation: C₂H₆O → C₂H₄O₂ + 4e⁻

Reduction: Cr₂O₇ + 6e⁻  → 2Cr⁺³

Now, balance the charge

Oxidation: C₂H₆O → C₂H₄O₂ + 4e⁻ + 4H⁺

Reduction: Cr₂O₇ + 6e⁻ + 14H⁺ → 2Cr⁺³

Now balance the oxygen atoms

Oxidation: C₂H₆O + H₂O → C₂H₄O₂ + 4e⁻ + 4H⁺

Reduction: Cr₂O₇ + 6e⁻ + 14H⁺ → 2Cr⁺³ + 7H₂O

Now, make electron gain equivalent to lost

Oxidation: C₂H₆O + H₂O → C₂H₄O₂ + 4e⁻ + 4H⁺ }  × 3

Reduction: Cr₂O₇ + 6e⁻ + 14H⁺ → 2Cr⁺³ + 7H₂O } × 2

Now,

Oxidation: 3C₂H₆O + 3H₂O → 3C₂H₄O₂ + 12e⁻ + 12H⁺

Reduction: 2Cr₂O₇ + 12e⁻ + 28H⁺ → 4Cr⁺³ + 14H₂O

Now, add the both equations

3CH₃CH₂OH + 2Cr₂O₇²⁻ + 16H⁺ → 3CH₃COOH + 4Cr³⁺ + 11H₂O

Thus from the above conclusion we can say that the balanced chemical equation is 3CH₃CH₂OH + 2Cr₂O₇²⁻ + 16H⁺ → 3CH₃COOH + 4Cr³⁺ + 11H₂O.

Learn more about the Balanced chemical equation here: brainly.com/question/26694427

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7 0
1 year ago
What type of solid is this? This solid has high melting point, does not conduct electricity, and does not dissolve in water. Met
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The awnser It is iconic
5 0
3 years ago
How to calculate moles
blondinia [14]

Explanation:

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For NaCl, the molar mass is 58.44 g/mol. Now we can use the rearranged equation. Mass (g) = No. Moles (mol) x Molar Mass (g/mol) = 1 x 58.44. = 58.44 g.

8 0
3 years ago
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In the following equation:
Luda [366]

Answer:

FeCl₃

Explanation:

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A simple way to determine which reagent is the limiting reactant is to convert all given data to moles then divide by the respective coefficients of the balanced equation. The smaller value will be the limiting reactant.

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Given =>  7/4 = 1.75*     9/3 = 3

*Smaller value => FeCl₃ is limiting reactant.  

NOTE: However, when working problems, one must use original mole values given.

   

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kotykmax [81]

Answer:

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