Answer:
Explanation:
To find the concentration; let's first compute the average density and the average atomic weight.
For the average density
; we have:

The average atomic weight is:

So; in terms of vanadium, the Concentration of iron is:

From a unit cell volume 

where;
= number of Avogadro constant.
SO; replacing
with
;
with
;
with
and
with 
Then:
![a^3 = \dfrac { n \Big (\dfrac{100}{[(100-C_v)/A_{Fe} ] + [C_v/A_v]} \Big) } {N_A\Big (\dfrac{100}{[(100-C_v)/\rho_{Fe} ] + [C_v/\rho_v]} \Big) }](https://tex.z-dn.net/?f=a%5E3%20%3D%20%5Cdfrac%20%20%20%7B%20n%20%5CBig%20%28%5Cdfrac%7B100%7D%7B%5B%28100-C_v%29%2FA_%7BFe%7D%20%5D%20%2B%20%5BC_v%2FA_v%5D%7D%20%5CBig%29%20%7D%20%20%20%20%7BN_A%5CBig%20%28%5Cdfrac%7B100%7D%7B%5B%28100-C_v%29%2F%5Crho_%7BFe%7D%20%5D%20%2B%20%5BC_v%2F%5Crho_v%5D%7D%20%5CBig%29%20%20%7D)
![a^3 = \dfrac { n \Big (\dfrac{100 \times A_{Fe} \times A_v}{[(100-C_v)A_{v} ] + [C_v/A_Fe]} \Big) } {N_A \Big (\dfrac{100 \times \rho_{Fe} \times \rho_v }{[(100-C_v)/\rho_{v} ] + [C_v \rho_{Fe}]} \Big) }](https://tex.z-dn.net/?f=a%5E3%20%3D%20%5Cdfrac%20%20%20%7B%20n%20%5CBig%20%28%5Cdfrac%7B100%20%5Ctimes%20A_%7BFe%7D%20%5Ctimes%20A_v%7D%7B%5B%28100-C_v%29A_%7Bv%7D%20%5D%20%2B%20%5BC_v%2FA_Fe%5D%7D%20%5CBig%29%20%7D%20%20%20%20%7BN_A%20%20%5CBig%20%28%5Cdfrac%7B100%20%5Ctimes%20%5Crho_%7BFe%7D%20%5Ctimes%20%20%5Crho_v%20%7D%7B%5B%28100-C_v%29%2F%5Crho_%7Bv%7D%20%5D%20%2B%20%5BC_v%20%5Crho_%7BFe%7D%5D%7D%20%5CBig%29%20%20%7D)
![a^3 = \dfrac { n \Big (\dfrac{100 \times A_{Fe} \times A_v}{[(100A_{v}-C_vA_{v}) ] + [C_vA_Fe]} \Big) } {N_A \Big (\dfrac{100 \times \rho_{Fe} \times \rho_v }{[(100\rho_{v} - C_v \rho_{v}) ] + [C_v \rho_{Fe}]} \Big) }](https://tex.z-dn.net/?f=a%5E3%20%3D%20%5Cdfrac%20%20%20%7B%20n%20%5CBig%20%28%5Cdfrac%7B100%20%5Ctimes%20A_%7BFe%7D%20%5Ctimes%20A_v%7D%7B%5B%28100A_%7Bv%7D-C_vA_%7Bv%7D%29%20%5D%20%2B%20%5BC_vA_Fe%5D%7D%20%5CBig%29%20%7D%20%20%20%20%7BN_A%20%20%5CBig%20%28%5Cdfrac%7B100%20%5Ctimes%20%5Crho_%7BFe%7D%20%5Ctimes%20%20%5Crho_v%20%7D%7B%5B%28100%5Crho_%7Bv%7D%20-%20C_v%20%5Crho_%7Bv%7D%29%20%5D%20%2B%20%5BC_v%20%5Crho_%7BFe%7D%5D%7D%20%5CBig%29%20%20%7D)
Replacing the values; we have:




Answer:
0,31%
Explanation:
For the reaction:
I₂ + 2 S₂O₃²⁻ → 2 I⁻ + S₄O₆²⁻
0,043 L × 0,117 M of sodium tiosulfate = 5,031x10⁻³ moles of S₂O₃²⁻
5,031x10⁻³ moles of S₂O₃²⁻ ×
= <em>2,5156x10⁻³ moles of I₂</em>
These moles of I₂ were produced from:
ClO⁻⁻ + 2 H⁺ + 2 I⁻ → I₂ + Cl⁻ + H2O
2,5156x10⁻³ moles of I₂ ≡ moles of NaClO
2,5156x10⁻³ moles of NaClO ×
=<em> 0,187 g of NaClO</em>
Thus, percentage composition by mass is:
=<em> 0,31%</em>
I hope it helps!
If you'd like the full working, here it is:
I calculated this by using the formula triangle.
Mass
Number Formula
Of moles Mass
To calculate the number if moles in a substance, you need to divide the Mass by the Formula mass. You get the formula mass by adding the atomic masses of the elements in the compound together. In this situation, H2O, it would be two hydrogen molecules plus one oxygen molecule which is 2 + 16. This is because the atomic mass of Hydrogen is 1 and the atomic mass of Oxygen is 16.
Now that we have the Formula mass we can go ahead and do the calculation since we already have the Mass. You do as follows:
Mass divided by Formula mass which is in this case - 25 divided by 18
By doing this calculation you will get the answer which is 1.38 moles which can be rounded to 1.4
Hope this helps :)
Answer:
The iron is in the +3 oxidation state, which is what the III means.