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telo118 [61]
3 years ago
10

Measurements show that the enthalpy of a mixture of gaseous reactants increases by 186.kJ during a certain chemical reaction, wh

ich is carried out at a constant pressure. Furthermore, by carefully monitoring the volume change it is determined that −179.kJ of work is done on the mixture during the reaction. Calculate the change in energy of the gas mixture during the reaction. Round your answer to 1 significant digit. kJ Is the reaction exothermic or endothermic? exothermic endothermic
Chemistry
1 answer:
pshichka [43]3 years ago
7 0
To begin with, as Delta H = variation in enthalpy is >0 , it means rxn is endothermic.
The rule says: Delta U = Delta H + W = 186 -179 = 7 kJ.
Where Delta U is variation in internal energy and W is the work done.
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2.53×10²³ atoms

Explanation:

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Solution : Given,

Mass of Ag_2O = 25.0 g

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Molar mass of Ag_2O = 231.7 g/mole

Molar mass of C_{10}H_{10}N_4SO_2 = 250.3 g/mole

Molar mass of AgC_{10}H_{9}N_4SO_2 = 357.1 g/mole

First we have to calculate the moles of Ag_2O and C_{10}H_{10}N_4SO_2.

\text{ Moles of }Ag_2O=\frac{\text{ Mass of }Ag_2O}{\text{ Molar mass of }Ag_2O}=\frac{25.0g}{231.7g/mole}=0.1079moles

\text{ Moles of }C_{10}H_{10}N_4SO_2=\frac{\text{ Mass of }C_{10}H_{10}N_4SO_2}{\text{ Molar mass of }C_{10}H_{10}N_4SO_2}=\frac{50.0g}{250.3g/mole}=0.1998moles

Now we have to calculate the limiting and excess reagent.

The balanced chemical reaction is,

Ag_2O(s)+2C_{10}H_{10}N_4SO_2(s)\rightarrow 2AgC_{10}H_9N_4SO_2(s)+H_2O(l)

From the balanced reaction we conclude that

As, 2 mole of C_{10}H_{10}N_4SO_2 react with 1 mole of Ag_2O

So, 0.1998 moles of C_{10}H_{10}N_4SO_2 react with \frac{0.1998}{2}=0.0999 moles of Ag_2O

From this we conclude that, Ag_2O is an excess reagent because the given moles are greater than the required moles and C_{10}H_{10}N_4SO_2 is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of AgC_{10}H_9N_4SO_2

From the reaction, we conclude that

As, 2 mole of C_{10}H_{10}N_4SO_2 react with 2 mole of AgC_{10}H_9N_4SO_2

So, 0.1998 mole of C_{10}H_{10}N_4SO_2 react with 0.1998 mole of AgC_{10}H_9N_4SO_2

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\text{ Mass of }AgC_{10}H_9N_4SO_2=(0.1998moles)\times (357.1g/mole)=71.35g

Therefore, the mass of silver sulfadiazine produced can be, 71.35 grams.

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