3
One from fe
And two from cl2
Color change
new substance formed
heat or light change
new smell
irreversible
For an aqueous solution of MgBr2, a freezing point depression occurs due to the rules of colligative properties. Since MgBr2 is an ionic compound, it acts a strong electrolyte; thus, dissociating completely in an aqueous solution. For the equation:
ΔTf<span> = (K</span>f)(<span>m)(i)
</span>where:
ΔTf = change in freezing point = (Ti - Tf)
Ti = freezing point of pure water = 0 celsius
Tf = freezing point of water with solute = ?
Kf = freezing point depression constant = 1.86 celsius-kg/mole (for water)
m = molality of solution (mol solute/kg solvent) = ?
i = ions in solution = 3
Computing for molality:
Molar mass of MgBr2 = 184.113 g/mol
m = 10.5g MgBr2 / 184.113/ 0.2 kg water = 0.285 mol/kg
For the problem,
ΔTf = (Kf)(m)(i) = 1.86(0.285)(3) = 1.59 = Ti - Tf = 0 - Tf
Tf = -1.59 celsius
Answer:
a. Kp=1.4


b.Kp=2.0 * 10^-4


c.Kp=2.0 * 10^5


Explanation:
For the reaction
A(g)⇌2B(g)
Kp is defined as:

The conditions in the system are:
A B
initial 0 1 atm
equilibrium x 1atm-2x
At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.
Replacing these values in the expression for Kp we get:

Working with this equation:

This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1
The general expression to solve these kinds of equations is:
(equation 1)
We just take the positive values from the solution since negative partial pressures don´t make physical sense.
Kp = 1.4


With x1 we get a partial pressure of:


Since negative partial pressure don´t make physical sense x1 is not the solution for the system.
With x2 we get:


These partial pressures make sense so x2 is the solution for the equation.
We follow the same analysis for the other values of Kp.
Kp=2*10^-4
X1=0.505
X2=0.495
With x1


Not sense.
With x2


X2 is the solution for this equation.
Kp=2*10^5
X1=50001

With x1


Not sense.
With x2


X2 is the solution for this equation.