Answer:
See image attached
Explanation:
a)
The full reaction mechanism of step 1 was obtained from Bartleby and attached to this answer. The steps involved in the reaction are:
1) Loss of Br- and formation of a carbocation
2) Attack of CH3CN on the carbocation
4) Formation of a quaternary nitrogen intermediate
5) Attack of water on the quaternary nitrogen intermediate
6) Loss of the water molecule
5) Formation of the amide product
b)
i) sodium hydroxide
ii) HCl
Water, Water is not a pure substance. It is a mixture, and Chromatography
Answer:
4.65 L of NH₃ is required for the reaction
Explanation:
2NH₃(g) + H₂SO₄(aq) → (NH₄)₂SO₄(s)
We determine the ammonium sulfate's moles that have been formed.
8.98 g . 1mol / 132.06 g = 0.068 moles
Now, we propose this rule of three:
1 mol of ammonium sulfate can be produced by 2 moles of ammonia
Therefore, 0.068 moles of salt were produced by (0.068 . 29) / 1 = 0.136 moles of NH₃. We apply the Ideal Gases Law, to determine the volume.
Firstly we do unit's conversions:
27.6°C +273 = 300.6 K
547.9 mmHg . 1 atm / 760 mmHg = 0.721 atm
V = ( n . R . T ) / P → (0.136 mol . 0.082 L.atm/mol.K . 300.6K) / 0.721 atm
V = 4.65 L