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enot [183]
3 years ago
6

For a particular reaction, ΔH° is 34.2 kJ and ΔS is 99.2 J/K. Assuming these values change very little with temperature, over wh

at temperature range is the reaction spontaneous in the forward direction?
Chemistry
2 answers:
Lynna [10]3 years ago
4 0

The calculation of temperature is done as follows:

T = ΔH°/ΔS°

= 34.2 kJ/mol / 99.2 × 10⁻³ kJ/molK

= 345 K

Since, ΔS° and ΔH° comes out to be positive for the given reaction. Hence, the given reaction is spontaneous at higher temperature and non spontaneous at lower temperature. Thus, it can be said that above 345 K, the given reaction will become spontaneous.

Nostrana [21]3 years ago
3 0

 Over 344.76 K  the  forward reaction will be spontaneous

 <u><em>calculation</em></u>

ΔG  = ΔH° -TΔs

if ΔG =0

therefore  0 =ΔH°-TΔs

ΔH°   = TΔs

divide  both side  by   Δs

T = ΔH°/Δs

convert 34.2 kj into j

 that  is 1 kj = 1000 j

        34.2 kj =? j

<em>by cross  multiplication</em>

=[34.2 kj x 1000j / 1 kj] = 34200 j

T  is therefore = 34200 j÷99.2 j/k =344.76 k

if  T is greater than  344.76 k  the forward reaction  will be spontaneous

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Answer:

  • A.) Gases are readily soluble in water at higher temperatures: FALSE
  • B.) Carbon dioxide gas will be less soluble in water when the partial pressure is low: TRUE
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Explanation:

The answer choices are:

  • A.) Gases are readily soluble in water at higher temperatures.
  • B.) Carbon dioxide gas will be less soluble in water when the partial pressure is low.
  • C.) Zinc sulfate is soluble in water.
  • D.) Propanol and heptane are miscible.
  • E.) Table salt dissolves in water to form a solution.

<h2>Solution</h2>

Let's see every statement

<u><em>A.) Gases are readily soluble in water at higher temperatures.</em></u>

This is false. At higher temperature, the gas molecules will have higher kinetic energy, meaning that they will move faster and escape more easily from the liquid phase. Thus, gases are less soluble at higher temperatures.

<u><em>B.) Carbon dioxide gas will be less soluble in water when the partial pressure is low.</em></u>

This is TRUE.

HIgher pressures "push" the gas molecules into the liquid phase. When more molecules get dissolved the pressure is partially relieved.

This relation is stated by Henry's Law: the solubility of gases in liquids is directly proportional to the pressure of the gases above the surface of the solution. Thus, carbon dioxide will me less soluble in water when the pressure is low.

<u><em>C.) Zinc sulfate is soluble in water.</em></u>

This is TRUE.

You must resort to the rules of solubility or search the properties of this salt.

Th solubility rules state that most sulfates are soluble in water. Exceptions are sulfates of Ag⁺,Ca²⁺, Sr²⁺, Ba²⁺, Hg²⁺, and Pb²⁺. Thus, you can expect that zinc sulfate is soluble in water.

<u><em>D.) Propanol and heptane are miscible.</em></u>

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Propanol is a polar compound. It is miscible with water because water is polar too. Heptane is not polar. Thus, following the rule that "like dissolves like" propanol and heptane are not miscible.

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<u><em>E.) Table salt dissolves in water to form a solution.</em></u>

This is TRUE.

This is a classical example of an ionic compound (sodium chloride) that is soluble in water (a polar solvent), showing the rule that polar solvents dissolve polar and ionic compounds.

It is also an everyday fact: rice, for instance, absorbs salt from water because the salt is dissolved in the water.

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