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Gennadij [26K]
3 years ago
15

Which is more acidic, 3-nitrophenol or 2-nitrophenol and why? Which is more basic, benzyl amine or aniline and why? Which is mor

e basic, triethylamine or diethylamine and why?
Chemistry
1 answer:
Anika [276]3 years ago
3 0

Answer:

2-nitrophenol is more acidic than 3-nitrophenol

benyl amine is more basic than aniline

dimethylamine is more basic than triethylamine

Explanation

Mesomeric effect stabilizes the anion formed when hydrogen of the  the -OH group in the 2-nitrophenol is lost. This mesomerism is most pronounced at the 2 and 4 position.

Stronger bases have more available lone pair of electrons. The lone pair of electrons in aniline is delocalized  over the ring. Hence it is unavailable for protonation while the lone pair on benzyl amine is available for protonation

Diethylamine is a stronger base because it has a balance of both inductive electron donation by alkyl groups, and solvation of the conjugate acid unlike triethylamine. Hence Diethylamine is a stronger base than triethylamine

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A first order reaction has a rate constant of 0.543 at 25 c and 6.47 at 47
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The activation energy Ea can be related to rate constant (k) at temperature (T) through the equation:

ln(k2/k1) = Ea/R[1/T1 - 1/T2]

where :

k1 is the rate constant at temperature T1

k2 is the rate constant at temperature T2

R = gas constant = 8.314 J/K-mol

Given data:

k1 = 0.543 s-1; T1 = 25 C = 25+273 = 298 K

k2 = 6.47 s-1; T = 47 C = 47+273 = 320 K

ln(6.47/0.543) = Ea/8.314 [1/298 - 1/320]

2.478 = 2.774 *10^-5 Ea

Ea = 0.8934*10^5 J = 89.3 kJ

5 0
3 years ago
25 points! Help please
Sedbober [7]

Answer:

I think its b

Explanation:

but I wouldn't depend on this answer

4 0
3 years ago
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Explain how a hurricane poses a threat to life and the biosphere. Use complete sentences.
Snezhnost [94]

Answer:

A hurricane can cause extreme damage to the biosphere and the geosphere. A hurricane can leave water standing therefore sinking itself into the geosphere. The biosphere can be permanently effected because it can kill, injure, and destroy the biosphere and what the biosphere creates (buildings, parks).

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A formic acid buffer solution contains 0. 20 m h c o o h hcooh and 0. 24 m h c o o − hcoox−. the pka of formic acid is 3. 75. wh
irina1246 [14]

A buffer solution contains an equivalent amount of acid and base. The pH of the solution with an acid dissociation constant (pKa) value of 3.75 is 3.82.

<h3>What is pH?</h3>

The amount of hydrogen or the proton ion in the solution is expressed by the pH. It is given by the sum of pKa and the log of the concentration of acid and bases.

Given,

Concentration of salt [HCOO⁻] = 0.24 M

Concentration of acid [HCOOH] = 0.20 M

The acid dissociation constant (pKa) = 3.75

pH is calculated from the Hendersons equation as,

pH = pKa + log [salt] ÷ [acid]

pH = 3.75 + log [0.24] ÷ [0.20]

= 3.75 + log (1.2)

= 3.75 + 0.079

= 3.82

Therefore, 3.82 is the pH of the buffer.

Learn more about pH here:

brainly.com/question/27181245

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2 years ago
The specific heat of aluminum is s 9.00 J/g C how much energy is needed to raise the temperature of 20.0 g block of aluminum fro
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E=MC(delta)T
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